Zobrazeno 1 - 10
of 25
pro vyhledávání: '"Adam J. V. Marwitz"'
Publikováno v:
Organometallics. 32:317-322
The Lewis acidic fluoroarylborane B(o-HC6F4)3 (2) was prepared and its Lewis acid strength assessed in comparison to the known, related boranes B(C6F5)3 (1) and B(p-HC6F4)3 (3). Experimental methods based on spectroscopic probes and equilibrium measu
BN-substituted diphenylacetylene: a basic model for conjugated π-systems containing the BN bond pair
Autor:
Monica Vasiliu, Shih-Yuan Liu, Lev N. Zakharov, Adam J. V. Marwitz, Ashley N. Lamm, David A. Dixon
Publikováno v:
Chem. Sci.. 3:825-829
We report the synthesis, structural characterization, and optoelectronic properties of BN-Tolan 1 and Bis-BN-Tolan 2, one of the simplest conjugated systems containing the BN bond pair. BN-tolans 1 and 2 display absorption and emission properties tha
Publikováno v:
Journal of the American Chemical Society. 133:10026-10029
A chemically competent indirect pathway for the activation of dihydrogen by the nonmetal Lewis acid/Lewis base pair tBu3P/B(C6F5)3 is described. The reaction between tBu3P and B(C6F5)3 produces [tBu3PH]+[FB(C6F5)3]− and the known phosphinoborane p-
Publikováno v:
Angewandte Chemie International Edition. 49:7444-7447
1,2-Dihydro-1,2-azaborine is a six-membered aromatic heterocycle that is isoelectronic with benzene through the replacement of a C=C unit in benzene with an isoelectronic B–N unit.[1,2] Since the pioneering work by Dewar et al.,[3,4] significant ad
Publikováno v:
Angewandte Chemie. 121:991-995
Autor:
Andrey Y. Khalimon, Adam J. V. Marwitz, James M. Blackwell, Bryan K. Shaw, Masood Parvez, Warren E. Piers
Publikováno v:
Dalton transactions (Cambridge, England : 2003). 44(41)
A series of molecules capable of releasing of the strong organometallic Lewis acid B(C6F5)3 upon exposure to 254 nm light have been developed. These photo Lewis acid generators (PhLAGs) can now serve as photoinitiators for several important B(C6F5)3-
Publikováno v:
Organic Letters. 8:3931-3934
Unsaturated fatty acids are nitrated endogenously to produce nitrated lipids. Recent studies have shown that these nitrated lipids have high chemical reactivity and profound biological implications. We report an efficient, scalable synthesis which is
Publikováno v:
Angewandte Chemie. 121:6949-6951
Publikováno v:
ChemInform. 43
The chemistry of organoboron compounds has been primarily dominated by their use as powerful reagents in synthetic organic chemistry. Recently, the incorporation of boron as part of a functional target structure has emerged as a useful way to generat
The chemistry of organoboron compounds has been primarily dominated by their use as powerful reagents in synthetic organic chemistry. Recently, the incorporation of boron as part of a functional target structure has emerged as a useful way to generat
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::f44d9ed07912e9bf084b7a86eedc9740
https://europepmc.org/articles/PMC3698317/
https://europepmc.org/articles/PMC3698317/