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pro vyhledávání: '"Adam J Kurish"'
Publikováno v:
Tetrahedron Letters. 44:2449-2453
The Grubbs second generation ruthenium catalyst was employed for the cross metathesis between α- and β-C-allyl glycosides and suitably protected l-vinyl glycines to furnish olefinic products in 57–94% yields. Hydrogenation afforded the C-glycosyl
Publikováno v:
Organic letters. 7(15)
C-Glycosyl amino acids represent stable mimics of monomeric units within natural O-linked glycoproteins. Olefin cross-metathesis has been used to provide alkene precursors for a mercury(II)-mediated cyclization, yielding alpha-C-glucosyl serine and a