Zobrazeno 1 - 10
of 31
pro vyhledávání: '"Adam J, Pearce"'
Autor:
Xiaofan Jia, Hannah S. Nedzbala, Samuel R. Bottum, James F. Cahoon, Javier J. Concepcion, Carrie L. Donley, Albert Gang, Qi Han, Nilay Hazari, Matthew C. Kessinger, Matthew R. Lockett, James M. Mayer, Brandon Q. Mercado, Gerald J. Meyer, Adam J. Pearce, Conor L. Rooney, Renato N. Sampaio, Bo Shang, Hailiang Wang
Publikováno v:
Inorganic Chemistry. 62:2359-2375
Publikováno v:
Journal of the American Chemical Society. 144:8641-8648
Autor:
Connor W. Frye, Dominic T. Egger, Errikos Kounalis, Adam J. Pearce, Yukun Cheng, Ian A. Tonks
Publikováno v:
Chemical Science. 13:1469-1477
Alkyne diimination to unsymmetric α-diimines can be achieved via multicomponent reaction of Ti imidos and C-nitrosos. C-nitroso [4 + 2] cycloaddition across a diazatitanacyclohexadiene initiates cascading retrocycloadditions, liberating the α-diimi
Autor:
Alexander C. Wotal, Rachel J. Dunscomb, Benjamin R. Reiner, Robin P. Harkins, Ian A. Tonks, Adam J. Pearce
Publikováno v:
J Am Chem Soc
Pyrazoles are an important class of heterocycles found in a wide range of bioactive compounds and pharmaceuticals. Pyrazole synthesis often requires hydrazine or related reagents where an intact N-N bond is conservatively installed into a pyrazole pr
Autor:
Connor W, Frye, Dominic T, Egger, Errikos, Kounalis, Adam J, Pearce, Yukun, Cheng, Ian A, Tonks
Publikováno v:
Chemical science. 13(5)
α-Diimines are commonly used as supporting ligands for a variety of transition metal-catalyzed processes, most notably in α-olefin polymerization. They are also precursors to valuable synthetic targets, such as chiral 1,2-diamines. Their synthesis
Autor:
Connor W. Frye, Yukun Cheng, Dominic T. Egger, Ian A. Tonks, Errikos Kounalis, Adam J. Pearce
α-Diimines are commonly used as supporting ligands for a variety of transition metal-catalyzed processes, most notably in α-olefin polymerization. They are also precursors to valuable synthetic targets, such as chiral 1,2-diamines. Their synthesis
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::e3689fa38588503e1207303f1a5178e0
https://doi.org/10.33774/chemrxiv-2021-dmdqr
https://doi.org/10.33774/chemrxiv-2021-dmdqr
Autor:
Peter L. Dunn, Sudipta Chatterjee, Kyle M. Lancaster, Adam J. Pearce, Ian A. Tonks, Samantha N. MacMillan
Publikováno v:
Inorganic Chemistry. 58:11762-11772
The synthesis and reactivity of a new trimetallic complex Ti(NP)4Ni2 (NP = 2-diphenylphosphinopyrrolide) (3) is reported. Single-crystal X-ray diffraction and X-ray absorption studies point to a un...
Publikováno v:
Organometallics
Simple Ti amide complexes are shown to act as sources for masked Ti(II) intermediates via several pathways, as demonstrated through the investigation of a unique Ti-catalyzed nitrene-coupled transfer hydrogenation of 3-hexyne. This reaction proceeds
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::a48fad7a471d77b4b30cf6dc9a1da28c
https://europepmc.org/articles/PMC8315702/
https://europepmc.org/articles/PMC8315702/
Publikováno v:
Chemical Communications. 54:6891-6894
Catalytic oxidative nitrene transfer from azides with the early transition metals is rare, and has not been observed without the support of redox noninnocent spectator ligands. Here, we report the formal [2+2+1] coupling of azides and alkynes via Ti(
Autor:
Evan P. Beaumier, Ian A. Tonks, Zachary W. Davis-Gilbert, Xin Yi See, Jacob A. Larsen, T. Alex Wheeler, Adam J. Pearce, Peter L. Dunn
Publikováno v:
Organometallics. 36:1383-1390
Low-valent TiII species have typically been synthesized by the reaction of TiIV halides with strong metal reductants. Herein we report that TiII species can be generated simply by reacting TiIV imido complexes with 2 equiv of alkyne, yielding a metal