Zobrazeno 1 - 10
of 26
pro vyhledávání: '"Adam F. Sapnik"'
Autor:
Adam F. Sapnik, Chao Sun, Joonatan E. M. Laulainen, Duncan N. Johnstone, Rik Brydson, Timothy Johnson, Paul A. Midgley, Thomas D. Bennett, Sean M. Collins
Publikováno v:
Communications Chemistry, Vol 6, Iss 1, Pp 1-12 (2023)
Abstract Intentionally disordered metal–organic frameworks (MOFs) display rich functional behaviour. However, the characterisation of their atomic structures remains incredibly challenging. X-ray pair distribution function techniques have been pivo
Externí odkaz:
https://doaj.org/article/3b1164fb56f6460a9834ad2ac1b4398e
Autor:
Adam F. Sapnik, Irene Bechis, Alice M. Bumstead, Timothy Johnson, Philip A. Chater, David A. Keen, Kim E. Jelfs, Thomas D. Bennett
Publikováno v:
Nature Communications, Vol 13, Iss 1, Pp 1-13 (2022)
Structural disorder in materials is challenging to characterise. Here, the authors use multivariate analysis of atomic pair distribution functions to study structural collapse and melting of metal–organic frameworks, revealing powerful mechanistic
Externí odkaz:
https://doaj.org/article/85ffc094b2784171ad43e1f019862885
Autor:
Adam F. Sapnik, Irene Bechis, Sean M. Collins, Duncan N. Johnstone, Giorgio Divitini, Andrew J. Smith, Philip A. Chater, Matthew A. Addicoat, Timothy Johnson, David A. Keen, Kim E. Jelfs, Thomas D. Bennett
Publikováno v:
Nature Communications, Vol 12, Iss 1, Pp 1-12 (2021)
The structures of amorphous MOFs are challenging to characterise. Here the authors use electron microscopy and pair distribution function methods, coupled with a polymerisation-based algorithm to determine the atomic structure of Fe-BTC, demonstratin
Externí odkaz:
https://doaj.org/article/54151337285c432a92704f51dfb2d1df
Autor:
Louis Longley, Courtney Calahoo, René Limbach, Yang Xia, Joshua M. Tuffnell, Adam F. Sapnik, Michael F. Thorne, Dean S. Keeble, David A. Keen, Lothar Wondraczek, Thomas D. Bennett
Publikováno v:
Nature Communications, Vol 11, Iss 1, Pp 1-12 (2020)
Metal-organic frameworks constitute a family of glass formers that is distinct from those that are polymeric, metallic, or inorganic. Here the authors show that they can be combined with different inorganic aluminophosphate glasses to produce a compo
Externí odkaz:
https://doaj.org/article/d975c5b704394c16be07dd65a701fb30
Autor:
Alice M. Bumstead, Celia Castillo-Blas, Ignas Pakamorė, Michael F. Thorne, Adam F. Sapnik, Ashleigh M. Chester, Georgina Robertson, Daniel J. M. Irving, Philip A. Chater, David A. Keen, Ross S. Forgan, Thomas D. Bennett
Publikováno v:
Chemical communications (Cambridge, England).
The chemistries that can be incorporated within melt-quenched zeolitic imidazolate framework (ZIF) glasses are currently limited. Here we describe the preparation of a previously unknown purine-containing ZIF which we name ZIF-UC-7. We find that it m
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::e84562f6877ada3044b5a56fddc83cbb
https://pubmed.ncbi.nlm.nih.gov/36541403
https://pubmed.ncbi.nlm.nih.gov/36541403
Autor:
Alice M. Bumstead, Michael F. Thorne, Adam F. Sapnik, Celia Castillo-Blas, Giulio I. Lampronti, Thomas D. Bennett
Publikováno v:
Dalton transactions (Cambridge, England : 2003). 51(36)
An in-depth comparison of the thermal behaviour of three zni topology ZIFs—ZIF-zni, ZIF-61 and ZIF-zni-NH2—allowed the sensitivity of melting to changes in chemical composition to be investigated.
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::6ee58155fedaede92433f1e0f337524e
https://pubmed.ncbi.nlm.nih.gov/36039615
https://pubmed.ncbi.nlm.nih.gov/36039615
Autor:
Dean S. Keeble, Alice M. Bumstead, David A. Keen, Adam F. Sapnik, Michael F. Thorne, Lauren N. McHugh, Celia Castillo-Blas, Thomas D. Bennett, Phillip A. Chater, Maria Diaz Lopez
Publikováno v:
Chemical Communications. 57:9272-9275
Zeolitic imidazolate frameworks (ZIFs) can be melt-quenched to form glasses. Here, we present an alternative route to glassy ZIFs via mechanically induced amorphisation. This approach allows various glassy ZIFs to be produced in under 30 minutes at r
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::3bd3a1aa1f9e5a32964407160dad3760
https://doi.org/10.1039/d1cc03469c
https://doi.org/10.1039/d1cc03469c
Autor:
Adam F. Sapnik, Christopher W. Ashling, Seok J. Lee, Shane G. Telfer, Timothy Johnson, Lauren K. Macreadie, Thomas D. Bennett
Publikováno v:
Journal of Materials Chemistry A. 9:27019-27027
Disordered metal–organic frameworks are emerging as an attractive class of functional materials, however their applications in gas storage and separation have yet to be fully explored. Here, we investigate gas adsorption in the topologically disord
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::28d59c9bb38d825bb4506cdfd2532c50
https://doi.org/10.1039/d1ta08449f
https://doi.org/10.1039/d1ta08449f
Autor:
Alice M. Bumstead, Ignas Pakamorė, Kieran D. Richards, Michael F. Thorne, Sophia S. Boyadjieva, Celia Castillo-Blas, Lauren N. McHugh, Adam F. Sapnik, Dean S. Keeble, David A. Keen, Rachel C. Evans, Ross S. Forgan, Thomas D. Bennett
Melt-quenched metal-organic framework (MOF) glasses have gained significant interest as the first new category of glass reported in 50 years. In this work, an amine-functionalized zeolitic imidazolate framework (ZIF), denoted ZIF-UC-6, was prepared a
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::e523d545f0a6677d209757a7e44d80f3
https://eprints.gla.ac.uk/265812/1/265812.pdf
https://eprints.gla.ac.uk/265812/1/265812.pdf
Publikováno v:
Chemical Science
This perspective links the synthesis of MOF Gels to the formation of MOF-monoliths and their resultant properties and application.
The synthesis of metal–organic frameworks (MOFs) has, to date, largely been in the form of crystalline powders.
The synthesis of metal–organic frameworks (MOFs) has, to date, largely been in the form of crystalline powders.
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::7e3e5a49526556884c8f1d254ca8e175
https://doi.org/10.1039/c9sc04961d
https://doi.org/10.1039/c9sc04961d