Zobrazeno 1 - 10
of 178
pro vyhledávání: '"Ad Oskam"'
Publikováno v:
Recueil des Travaux Chimiques des Pays-Bas. 92:427-441
Normal coordinate calculations of vinyl fluoride, chloride, bromide and iodide are reviewed. Modified Valence Force Fields are reported, by making use of published vibrational data of all deuterated isotopic species and observed Coriolis constants. T
Publikováno v:
Inorganic Chemistry. 42:851-858
The structure, bonding, and vibrational properties of the mixed MLaX(4) (M = Na, K, Cs; X = F, Cl, Br, I) rare earth/alkali metal halide complexes have been studied using the MP2 method in conjunction with polarized triple-zeta valence basis sets and
Publikováno v:
Recueil des Travaux Chimiques des Pays-Bas. 105:372-374
Liquid Xenon (LXe) appears to be an ideal solvent for the study of reactive intermediates in photochemical reactions because of its complete inertness and transparency in both the IR and UV/Visible spectral regions. Photolysis of a H2-doped solution
Theoretical Study of Mixed LiLnX4 (Ln = La, Dy; X = F, Cl, Br, I) Rare Earth/Alkali Halide Complexes
Publikováno v:
Inorganic Chemistry. 39:6001-6008
The structure, bonding and vibrational properties of the mixed LiLnX4 (Ln = La, Dy; X = F, Cl, Br, I) rare earth/alkali halide complexes were studied using various quantum chemical methods (HF, MP2 and the Becke3-Lee-Yang-Parr exchange-correlation de
Autor:
Ad Oskam, D. M. Martino, Derk J. Stufkens, Cornelis J. Kleverlaan, J. van Slageren, H. van Willigen
Publikováno v:
Applied Magnetic Resonance. 15:203-214
A Fourier transform EPR (FT-EPR) study was made of the photochemistry of [Re(R)(CO)3 (α-diimine)] and [Ru(E)(R)(CO)2(α-diimine)] complexes, where R = alkyl or benzyl, E = I or SnPh3, and α-diimine = 4,4′-dimethyl-2,2′-bipyridine (DMB) orN,N′
Autor:
Anthony L. Spek, Nora Veldman, Kees Goubitz, Derk J. Stufkens, Maxim P. Aarnts, Jan Fraanje, Ad Oskam
Publikováno v:
Journal of Organometallic Chemistry. 531:191-205
This article describes the syntheses, structures and spectroscopic (IR, Raman, NMR, visible absorption) properties of novel metalmetal bonded complexes of the type trans,cis-Ru(E)(E′)(CO)2(iPrDAB) in which E Br, Me, SnPh3, Mn(CO)5 or Re(C
Publikováno v:
Inorganica Chimica Acta. 256:93-105
This article describes the syntheses, structures and spectroscopic (IR, Raman, NMR, visible absorption) properties of novel inorganometallic complexes of the type Ru(E)(E′)(CO) 2 (iPr-DAB) in which E represents a Cl, Me, SnPh 3 or PbPh 3 group and
Publikováno v:
Vibrational Spectroscopy. 14:87-93
The IR and Raman spectra of gaseous and liquid tetraethoxytitanium, Ti(OC 2 H 5 ) 4 , have been recorded and an assignment has been made. Comparison of the spectra clearly shows the polymeric nature of tetraethoxytitanium in the liquid phase and mono
Publikováno v:
Inorganica Chimica Acta, 247, 215-229. Elsevier
The spectroscopic properties and photochemistry of the complexes Mn(R)(CO)3(R′-DAB) (R=Me, Bz; R′=iPr, pTol) are reported. The UV-photoelectron spectrum of Mn(Me)(CO)3(iPr-DAB) shows that the σ(MnMe) orbital has a higher ionization potential
Publikováno v:
J. Chem. Soc., Faraday Trans.. 92:3259-3265
The influence of a second metal oxide (tungsten oxide, molybdenum oxide, nickel oxide, cobalt oxide) upon a V2O5/Al2O3 catalyst has been investigated by a combined Raman and IR study under dehydrated conditions. The presence of tungsten or molybdenum