Iron(III)-Catalyzed Intramolecular Friedel-Crafts Alkylation of Electron-Deficient Arenes with π-Activated Alcohols

Autor: Michele Tragni, Achille Umani-Ronchi, Marco Bandini

Publikováno v: Advanced Synthesis & Catalysis. 351:2521-2524

“Deficient” but “efficient”, the first example of catalytic Friedel-Crafts alkylation of arenes, carrying electron-withdrawing groups, with alcohols is reported. The optmized iron(III) chloride (97%) FeCl3 catalyzed allylation, benzylation an

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::b967cdefbc9a5ddc289a3d91a4bdac4e
https://doi.org/10.1002/adsc.200900441

Highly Efficient Molybdenum(II)-Catalyzed Intramolecular Allylic Alkylation of Arenes

Autor: Achille Umani-Ronchi, Marco Bandini, Astrid Eichholzer, Peter Kotrusz

Publikováno v: Advanced Synthesis & Catalysis. 350:531-536

The Friedel-Crafts-type intramolecular allylic alkylation of simple arenes is performed in the presence of a catalytic amount of [Mo(II) (CO) 4 Br 2 ] 2 (2.5 mol%). The moisture-tolerant protocol provided a mild and direct access to a large library o

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::08031efb1c3e9b0e5baf76ad2562d182
https://doi.org/10.1002/adsc.200700607

Synthesis, structural characterization, and catalytic activity of chiral diamine and diimine Pd(II)-complexes

Autor: Magda Monari, Marco Bandini, Fabio Piccinelli, Simona Tommasi, Achille Umani-Ronchi, Vincenzo G. Albano

Publikováno v: Inorganica Chimica Acta. 360:1000-1008

A combined catalytic and crystallographic investigation on the effectiveness of chiral diamino-bithiophene (2) and the corresponding diimino molecules (1) as chiral ligands for Pd(II) catalyzed transformations is presented. In particular, a systemati

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::5d8b68c5eeea6733490047ee14a3b694
https://doi.org/10.1016/j.ica.2006.07.096

Innovative Catalytic Protocols for the Ring‐Closing Friedel–Crafts‐Type Alkylation and Alkenylation of Arenes

Autor: Marco Bandini, Simona Tommasi, Achille Umani‐Ronchi, Enrico Emer

Publikováno v: European Journal of Organic Chemistry. 2006:3527-3544

Over the past years an astonishing number of highly chemo- and regioselective intramolecular Friedel–Crafts (IMFC)-type alkylations of aromatic compounds have been described in the literature that allow remarkable synthetic shortcuts for the prepar

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::778cf1311d7bd61b8ece66cb06d4c8d5
https://doi.org/10.1002/ejoc.200500995

Novel Chiral Diamino-Oligothiophenes as Valuable Ligands in Pd-Catalyzed Allylic Alkylations. On the 'Primary' Role of 'Secondary' Interactions in Asymmetric Catalysis

Autor: Achille Umani-Ronchi, Magda Monari, Manuela Melucci, Vincenzo G. Albano, Simona Tommasi, Marco Bandini, Fabio Piccinelli

Publikováno v: Advanced synthesis & catalysis
347 (2005): 1507–1512. doi:10.1002/adsc.200505109
info:cnr-pdr/source/autori:Bandini, Marco (2); Melucci, Manuela (1); Umani-Ronchi, Achille (2); Piccinelli, Fabio (2); Tommasi, Simona (2); Monari, Magda (2); Albano, Vincenzo Giulio (2)/titolo:Novel chiral diamino-oligothiophenes as valuable ligands in Pd-catalyzed allylic alkylations. On the "primary" role of "secondary" interactions in asymmetric catalysis/doi:10.1002%2Fadsc.200505109/rivista:Advanced synthesis & catalysis (Print)/anno:2005/pagina_da:1507/pagina_a:1512/intervallo_pagine:1507–1512/volume:347

A new class of chiral C 2 -symmetrical diamino-oligothiophenes is described to be effective in catalyzing Pd-mediated asymmetric allylic alkylations in a highly enantioselective manner. The combination of experimental as well as crystallographic evid

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::9e14450a2bbb7c3519b3576ab53ca619
https://doi.org/10.1002/adsc.200505109