Electrochemical oxidation of aliphatic carboxylates: Kinetics, thermodynamics, and evidence for a shift from a concerted to a stepwise mechanism in the presence of water

Autor: Abdel Latif, Marwa K.

The mechanism and the oxidation potential of the dissociative single electron transfer for tetra-n-butylammonium acetate has been investigated via conventional (cyclic voltammetry) and convolution voltammetry. The oxidation potential for tetra-n-buty

Externí odkaz: http://hdl.handle.net/10919/82522

Does Metal Ion Complexation Make Radical Clocks Run Fast? An Experimental Perspective

Autor: Abdel Latif, Marwa K., Spencer, Jared N., Paradzinsky, Mark, Tanko, James M.

Publikováno v: The Journal of Physical Chemistry - Part A; 20240101, Issue: Preprints

Does Metal Ion Complexation Make Radical Clocks Run Fast? An Experimental Perspective.

Autor: Abdel Latif MK; Department of Chemistry, Virginia Polytechnic Institute And State University , Blacksburg, Virginia 24061, United States., Spencer JN; Department of Chemistry, Virginia Polytechnic Institute And State University , Blacksburg, Virginia 24061, United States., Paradzinsky M; Department of Chemistry, Virginia Polytechnic Institute And State University , Blacksburg, Virginia 24061, United States., Tanko JM; Department of Chemistry, Virginia Polytechnic Institute And State University , Blacksburg, Virginia 24061, United States.

Publikováno v: The journal of physical chemistry. A [J Phys Chem A] 2017 Dec 28; Vol. 121 (51), pp. 9682-9686. Date of Electronic Publication: 2017 Dec 14.