A Facile Isomerization Procedure for the Access to Thermodynamic Silyl Enol Ethers

Autor: Jean-Marie Poirier, Abdallah Deyine, Malika Mammeri, Gilles Dujardin

Publikováno v: Synthetic Communications. 28:1817-1821

Efficient access to thermodynamically favoured silyl enol ethers deriving from α,α′-dienolizable ketones was produced via easy-made NEt3HCl-mediated isomerization of a regioisomeric mixture of O-silylated products. † deceased on 7 may 1997 § P

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::b705b2e6445e9de47910b0681a6174da
https://doi.org/10.1080/00397919808007012

1,3-Dipolar cycloadditions of nitrones to α,β-unsaturated γ-lactams derived from (S)-pyroglutaminol

Autor: Angèle Chiaroni, N. Dahuron, D. Griffart‐Brunet, Nguyen Van Bac, Nicole Langlois, Abdallah Deyine, Claude Riche, Jean-Marc Delcroix

Publikováno v: Tetrahedron. 51:3571-3586

α,β-Unsaturated γ-lactams undergo regio- and stereoselective 1,3-dipolar cycloadditions with N-benzyl and N-methyl nitrones and can act as acceptors in conjugate addition of N-methylhydroxylamine. These reactions give access to highly functionaliz

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::3cbc37f327538ce106e86fc9a8d7e1d2
https://doi.org/10.1016/0040-4020(95)00100-m

ChemInform Abstract: 2-Alkoxy-3-oxoalkyl-tetrahydropyrans and -tetrahydrofurans: Versatile Intermediates in Heterocyclic Synthesis

Autor: Gérard Plé, Abdallah Deyine, Jean-Marie Poirier, Gilles Dujardin, Pierre Duhamel

Publikováno v: ChemInform. 27

A new Lewis acid-catalysed Michael-type addition of heterocyclic enol ethers to hemiacetal vinylogues 1 or to enones in the presence of a hydroxylic compound is described. The 1,5-keto acetals 3 so obtained have been studied with a view to synthetic

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::da1414408455dce52b1e1ccfe2838046
https://doi.org/10.1002/chin.199602058

Design of silicon-based misonidazole analogues and (18)F-radiolabelling

Autor: Catherine Fiol-Petit, Rabah Azzouz, Laurent Bischoff, Corinne Fruit, Pierre Bohn, Abdallah Deyine, Laetitia Bailly, Pierre Vera, Francis Marsais

Publikováno v: Nuclear Medicine and Biology
Nuclear Medicine and Biology, Elsevier, 2009, 36 (8), pp.895-905. ⟨10.1016/j.nucmedbio.2009.06.004⟩
Nuclear Medicine and Biology, 2009, 36 (8), pp.895-905. ⟨10.1016/j.nucmedbio.2009.06.004⟩

International audience; INTRODUCTION: Development of new (18)F-labeled tracers for positron emission tomography (PET) imaging is increasingly important. Herein, we described the synthesis of silicon analogues of [(18)F]fluoromisonidazole in order to

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::5134fa5ea9581a7545319cf0be76dc68
https://pubmed.ncbi.nlm.nih.gov/19875046

ChemInform Abstract: A Short Formal Synthesis of (.+-.)-Perhydrohistrionicotoxin

Autor: Jean-Marie Poirier, Pierre Duhamel, Abdallah Deyine

Publikováno v: ChemInform. 39

The reaction of a silyl enol ether bearing a nitrogen atom with a hemiacetal vinylog in the presence of a catalytic amount of boron trifluoride etherate led to the corresponding ketoaldehyde. The cyclisation of the ketoaldehyde into azaspiroenone and

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::8d90ce000f8780303e794b32527ad59d
https://doi.org/10.1002/chin.200822203