Zobrazeno 1 - 10
of 51
pro vyhledávání: '"Aase Hvidt"'
Publikováno v:
Fluid Phase Equilibria. 171:151-164
Densities of binary aqueous solutions of d -fructose (abbreviated as FR hereinafter) were determined in a much wider mole fraction range than available in literature. In contrast to hydrophobic solutes, the partial molar volume of FR, VFR, does not s
Autor:
Peter Westh, Aase Hvidt
Publikováno v:
Journal of Solution Chemistry. 27:395-402
Apparently contradictory statements about the thermodynamics of aqueous protein solutions and of hydrophobic effect are quoted and discussed. Some credibility is found in the divergent points of view and it is pointed out that they focus attention on
Excess partial molar enthalpies, entropies, Gibbs energies, and volumes in aqueous dimethylsulfoxide
Autor:
Peter Westh, Christa Trandum, John T. W. Lai, Frankie W. Lau, Aase Hvidt, Yoshikata Koga, Damon B. Robb, Gerda Nielsen
Publikováno v:
Journal of Solution Chemistry. 24:89-102
The excess partial molar enthalpies, the vapor pressures, and the densities of dimethylsulfoxide (DMSO)−H2O mixtures were measured and the excess partial molar Gibbs energies and the partial molar volumes were calculated for DMSO and for H2O. The v
Publikováno v:
Bulletin of the Chemical Society of Japan. 67:2393-2397
Liquid–solid phase diagram was determined in the water-rich region of aqueous 2-butoxyethanol. A solid addition compound was suggested with the composition = 0.0260, which melts incongruently at 269.5 K. The mixing scheme boundary separating two re
Autor:
Aase Hvidt, Henrik Nicolajsen
Publikováno v:
Cryobiology. 31:199-205
The equilibrium phase diagram of the system trehalose-water is studied by a combination of differential scanning calorimetry (DSC) and measurements of the solubility of trehalose in water. The behavior of samples of trehalose-water, and of trehalose-
Publikováno v:
Chemical Physics Letters. 217:245-248
Weak jump anomalies were observed in the temperature derivatives of the heat capacities of aqueous 2-butoxyethanol. The derivative, (∂ C p /∂ T ), is proportional to the third derivative of the Gibbs free energy with respect to T . The loci of th
Autor:
Aase Hvidt, Yoshikata Koga
Publikováno v:
Thermochimica Acta. 228:39-46
Available measurements of thermodynamic properties (enthalpy, Gibbs free energy and volume) of mixtures of water with 2-butoxyethanol at 25°C are discussed, with emphasis on the concentration dependence of the excess functions, and on the role playe
Autor:
Aase Hvidt, Peter Westh
Publikováno v:
Biophysical Chemistry. 46:27-35
Differential scanning calorimetry was used to measure the heat capacity of binary aqueous solutions of methanol, ethanol or 1-propanol over the whole composition range, and at temperatures ranging from 20°C down to the freezing temperature of the su
Publikováno v:
The Journal of Chemical Thermodynamics. 25:51-56
The densities of aqueous 2-butoxyethanol (BE); { x CH 3 (CH 2 ) 3 O(CH 2 ) 2 OH + (1- x H 2 O}, were measured at small increments in mole fraction x at the temperatures 288.15 K and 298.15 K, in the water-rich region: x V E m (BE) and V E m (H 2 O) w
Autor:
Aase Hvidt, Kim Borch
Publikováno v:
Thermochimica Acta. 175:53-58
Aqueous solutions of NaCl are studied by differential scanning calorimetry (DSC) during cooling, at scan rate 2 K min , to 218 K (−55°C) and subsequent heating to 288 K (+15°C). Hysteresis effects are reflected in the thermograrms. Two exothermic