Zobrazeno 1 - 10
of 70
pro vyhledávání: '"A.V. Purkina"'
Pecularities of Liquid Crystalline Order Formation in Polyesters with Irregular Chemical Composition
Publikováno v:
Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals. 299:199-203
Formation of liquid crystalline (LC) order in thermotropic main-chain random copolymers (containing mesogens of one type and spacers of different lengths) were investigated by IR spectroscopy, DSC, X-ray and polarized microscopy methods. It was demon
Publikováno v:
Macromolecular Symposia. 113:67-80
Conformational transitions in thermotropic main-chain polymers of complex chemical structure including homopolymers with possibility of conformational transformations in mesogens and random copolymers (CPLs) containing mesogens of the same type and s
Autor:
A.V. Purkina, Natalija A. Petukhova, Eugenij F. Panarin, Victor M. Denisov, Michael V. Solovskij
Publikováno v:
Macromolecular Chemistry and Physics. 197:2035-2046
Water-soluble N-vinyl-2-pyrrolidone (VP) copolymers containing phenol (or catechol) groups in the side chains were synthesized by reactions of copolymers of VP and crotonic acid (CA) with p-aminophenol and by reaction of p-nitrophenyl ester groups co
Autor:
Boris Volchek, A.V. Purkina
Publikováno v:
Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals. 265:209-224
With object to evaluate the effect of spacer chemical composition on chain conformation of thermotropic polymers in liquid crystalline (LC) state, linear and combined (main chain/side chain) polymers, containing fragment of malonic acid (FMA) in meth
Autor:
A.S. Khachaturov, Olga V. Nazarova, A.V. Purkina, E. F. Panarin, A.I. Kol'tsov, Solovskij Mikhail, V.M. Denisov
Publikováno v:
European Polymer Journal. 28:97-100
The copolymerizations of N-vinylpyrrolidone with N-hydroxyphthalimide and N-hydroxysuccinimide esters of acrylic, methacrylic and crotonic acids have been investigated. The reactivity ratios were determined, and kinetic investigations of the copolyme
Publikováno v:
Polymer Science U.S.S.R.. 33:1952-1959
The effect of the formation of LC order on the conformational structure of a number of thermotropic polyesters containing mesogenic and flexible fragments in the backbone with conformationally labile units in the mesogenic fragments has been studied.
Publikováno v:
Polymer Science U.S.S.R.. 32:1462-1467
Features of the orientation of thermotropic polyesters were observed by methods of IR spectroscopy with polarized and non-polarized radiation. Differences in the character of orientation of mesogenic fragments with respect to the shear direction are
Publikováno v:
Polymer Science U.S.S.R.. 19:371-377
IR and NMR spectroscopy has been used to show that the liquid-crystalline state of poly-(γ-benzyl-L-glutamate) solutions persists in the presence of the weak chloroacetic acid (CAA) as well as the strong difluorochloro-acetic acid (DFCAA). The unusu
Publikováno v:
Polymer Science U.S.S.R.. 22:930-939
The liquid crystal-isotropic solution phase equilibria have been studied by IR spectroscopy and polarized light microscopy on poly- γ -benzyl- L -glutamate concentrates in various solvents. The conditions under which the polymer exists in a non-aggr
Publikováno v:
Molecular Crystals and Liquid Crystals. 73:283-296
The diagrams of state for concentrated PBG solution in coordinates relating volume fraction-geometric asymmetry and volume fraction-temperature are investigated. The order parameter for macromolecules in the anisortropic phase is dettermined. The exp