Zobrazeno 1 - 10
of 104
pro vyhledávání: '"A.I. Kuzayev"'
Publikováno v:
Journal of Polymer Science: Polymer Symposia. 68:13-21
The techniques of heterogenization of homogeneous catalysts (molybdenum halogenized) for acetylene monomers polymerization on polymer supports have been worked out. The latter were carbon-chain polymers grafted with functional groups. The properties
Publikováno v:
Polymer Science U.S.S.R.. 29:2009-2016
Polymerization of epoxide compounds on exposure to complex catalysts of the onium type has been studied. It is shown that the action of the catalysts is due to their breakdown into active components—Lewis acid and tertiary amine. The MWD and struct
Publikováno v:
Polymer Science U.S.S.R.. 24:1636-1643
The parameters of MWD of oligobutadienes synthesized by the reaction of butadiene with 2-hexyl-lithium in a hydrocarbon medium have been determined by a combination of gel-permeation and gas-liquid chromatography methods. For calibration of the gel-c
Autor:
O.M. Ol'khova, A.I. Kuzayev
Publikováno v:
Polymer Science U.S.S.R.. 24:2520-2529
A study was made by GPC of MWD and molecular heterogeneity of products of cationic polymerization of epichlorohydrin by the action of THF-boron trifluoride in 1,2-dichloroethane solution. It was shown that up to 40% of the cyclic tetramer of epichlor
Publikováno v:
Polymer Science U.S.S.R.. 25:129-136
The MWD and composition of oligomers from alkylation of toluene with epichlorohydrin in the presence of boron trifluoride etherate have been investigated. With the aid of two-detector gel chromatographic analysis it was found that along with epichlor
Publikováno v:
Polymer Science U.S.S.R.. 29:2136-2142
The radical and cationic copolymerization of p-benzoquinone with phenyl acetylene are studied in bulk and in various solvents. The structures of the co-oligomers obtained (M = 750–1550) are determined by physicochemical methods. The weight loss of
Autor:
A.A. Brikenshtein, T.Ya. Kefeli, O.G. Sel'skaya, A.T. Radugina, A.I. Kuzayev, S.M. Kireyeva, V.T. Shashkova
Publikováno v:
Polymer Science U.S.S.R.. 28:788-794
The authors have studied the thermal, deformation-strength and other properties of polymers based on oligomer-homologues of oligocarbonate methacrylates. They demonstrate the peculiarity of the degradation of these polymers as compared with oligoeste
Publikováno v:
Polymer Science U.S.S.R.. 26:1139-1149
Thermodynamic functions of mixing have been evaluated for systems containing an epoxy oligomer and oligomer rubbers of different polarity. The functions were determined on the basis of an analysis of the diffusion data. An increase in the polarity of
Autor:
A.I. Kuzayev, S.V. Vinogradova, L.M. Bronshtein, P.M. Valetskii, Ye.Sh. Mirzoyeva, V.V. Korshak
Publikováno v:
Polymer Science U.S.S.R.. 31:2898-2905
The results of investigations of the processes involved in the immobilization of low-molecular complexes of rhodium, namely, rhodium chloride, carbonyl chloride and carbonyl, on PB and a poly(styrene-butadiene) block-copolymer are discussed. It is sh
Publikováno v:
Polymer Science U.S.S.R.. 26:1897-1902
Oligocarbonate methacrylates differing in their degree of polymerization have been synthesized through the interaction of ethylene- and diethyleneglycols with their chlorocarbon esters and ethylene glycol monomethacrylates. The composition and MWD of