Zobrazeno 1 - 10
of 52
pro vyhledávání: '"A.B. Dempster"'
Publikováno v:
Journal of Molecular Structure. 26:189-195
Analysis of the NMR spectra of 1,2,3-trichloropropane and 1,2,3-tribromopropane in various media shows the most stable conformer to be AG - . The populations of several conformera have been estimated by using pure trans and gauche coupling constants
Publikováno v:
Journal of Molecular Structure. 38:43-50
The time-dependent changes which are observed in the infrared and Raman spectra of samples of the two Hofmann aniline clathrates M(NH 3 ) 2 Ni(CN) 4 .an 2 {M = Cd(II), Ni(II), an = C 6 H 5 NH 2 } indicate the occurrence of a solid state ligand replac
Publikováno v:
Journal of Magnetic Resonance (1969). 16:235-242
The thermodynamic functions for internal rotation in three chloropropanes have been determined by nuclear magnetic resonance studies at low temperature. The coalescence temperature, free energy, enthalpy, and entropy of activation for internal rotati
Publikováno v:
Spectrochimica Acta Part A: Molecular Spectroscopy. 30:1183-1192
The Raman spectra of powdered, crystalline samples of the Hofmann-type benzene clathrates, Ni(NH 3 ) 2 Ni(CN) 4 .2C 6 H 6 , Ni(NH 3 ) 2 Ni(CN) 4 .2C 6 D 6 , Cd(NH 3 ) 2 Ni(CN) 4 .2C 6 H 6 and Cd(NH 3 ) 2 Ni(CN),.2C 6 D 6 have been measured at room te
Autor:
P.F. Swinton, A.B. Dempster
Publikováno v:
Journal of Molecular Structure. 21:373-385
The results of a combined infrared and nuclear magnetic resonance study of the meso (RS) and dl (RR) stereoisomers of 1,2,5,6-tetrachlorohexane and one meso (SRSR) form of 2,3,6,7-tetrachlorooctane are discussed with respect to the conformations of t
Publikováno v:
Spectrochimica Acta Part A: Molecular Spectroscopy. 31:245-253
The vapour phase infrared spectra of C6H5CH3, C6D5CH3 and C6H5CD3 have been measured in detail in the wavenumber regions associated with the “perpendicular” methyl (or methyl-d3) bond-stretching, antisymmetrical bending and rocking vibrations. Al
Publikováno v:
J. Chem. Soc., Dalton Trans.. :1746-1749
Infrared (200–4 000 cm–1) and Raman (300–3 500 cm–1) spectra are reported for metal(II) halide pyridine complexes of the following stoicheiometries: [MX2(py)2](M = Mn, Fe, Co, Ni, Cu, Zn, Cd, or Hg); [MX2(py)4](M = Fe, Co, or Ni); [MX2(py)2](
Autor:
A.B. Dempster
Publikováno v:
Journal of Molecular Structure. 23:193-202
Reconsideration of data from an earlier nuclear magnetic resonance study of 1,2-dichloropropane indicates that previously reported energy differences of the two G isomers compared to the T isomer (C-Cl bonds trans) should be reassigned for both the l
Publikováno v:
Spectrochimica Acta Part A: Molecular Spectroscopy. 31:1775-1784
The results are presented for an i.r. spectroscopic study of nickel and cadmium Hofmann-type clathrates, M(NH3)2Ni(CN)4,2G, M = Ni or Cd and G = thiophene, furan, pyrrole or phenol, with the exception of the cadmium clathrate with furan which could n
Autor:
A.B. Dempster, H. Uslu
Publikováno v:
Journal of Molecular Structure. 21:197-219
Normal coordinate analysis calculations have been made to determine the carbon-chlorine stretching (v(C-Cl)) frequencies of model rotational isomers of 1,2-dichloroethane, 1,2-dichloropropane, 1,3-dichloropropane, 1,5-dichloropentane and 1,2,3-trichl