Zobrazeno 1 - 10
of 141
pro vyhledávání: '"A. R. Mews"'
Publikováno v:
Zeitschrift für anorganische und allgemeine Chemie. 625:488-492
Publikováno v:
Journal of Fluorine Chemistry. 89:91-95
The reaction of pentafluorothio(fluorosulfonyl)ketene with formaldehyde has yielded the novel solid ether [SF 5 CH(SO 2 F)CH 2 ] 2 O, 1 . The crystal structure has been determined: crystal class tetragonal I4; a = b = 11.069(2) A, c = 6.0780(1) A; α
Three-coordinate sulphur(VI)-nitrogen species: an attempt to breathe some new life into an old topic
Autor:
R Mews
Publikováno v:
Coordination Chemistry Reviews. 158:233-273
Publikováno v:
Journal of Fluorine Chemistry. 60:109-123
Publikováno v:
ChemInform. 22
Publikováno v:
ChemInform. 23
Publikováno v:
ChemInform. 23
Publikováno v:
ChemInform. 25
Fluorine is particularly effective in stabilizing anionic charges in organic compounds. The SF 5 group, by comparison to the stabilizing effect of the CF 3 group, should allow one to synthesize a number of SF 5 containing anionic complexes. While the
Autor:
S.-J. CHEN, U. BEHRENS, E. FISCHER, R. MEWS, F. PAUER, G. M. SHELDRICK, D. STALKE, W.-D. STOHRER
Publikováno v:
ChemInform. 25
Publikováno v:
ChemInform. 29
The reaction of pentafluorothio(fluorosulfonyl)ketene with formaldehyde has yielded the novel solid ether [SF 5 CH(SO 2 F)CH 2 ] 2 O, 1 . The crystal structure has been determined: crystal class tetragonal I4; a = b = 11.069(2) A, c = 6.0780(1) A; α