Chelating chloride using binuclear lanthanide complexes in water

Autor: Carlson Alexander, James A. Thom, Alan M. Kenwright, Kirsten E. Christensen, Thomas Just Sørensen, Stephen Faulkner

Publikováno v: Alexander, C, Thom, J A, Kenwright, A M, Christensen, K E, Sørensen, T J & Faulkner, S 2023, ' Chelating chloride using binuclear lanthanide complexes in water ', Chemical Science, vol. 14, no. 5, pp. 1194-1204 . https://doi.org/10.1039/d2sc05417e

Halide recognition by supramolecular receptors and coordination complexes in water is a long-standing challenge. In this work, we report chloride binding in water and in competing media by pre-organised binuclear kinetically inert lanthanide complexe

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::d044f6ee9bfd115760e035cb790c3766
https://doi.org/10.1039/d2sc05417e

Tuning the anion binding properties of lanthanide receptors to discriminate nucleoside phosphates in a sensing array†

Autor: Sarah H. Hewitt, Fernanda Duarte, Mark R. J. Elsegood, Alan M. Kenwright, Romain Mailhot, Stephen J. Butler, Georgina Macey

Publikováno v: Chemical Science
Chemical science, 2020, Vol.11(14), pp.3619-3628 [Peer Reviewed Journal]

The development of synthetic receptors for the selective binding and discrimination of anions in water requires an understanding of how anions interact with these synthetic receptors. Molecules designed to differentiate nucleoside phosphate anions (e

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::7531306607abc90d6badd09f1ba3468a
http://europepmc.org/articles/PMC8152522

Optical Properties of Heavily Fluorinated Lanthanide Tris β-Diketonate Phosphine Oxide Adducts

Autor: Adam N. Swinburne, Madeleine H. Langford Paden, Tsz Ling Chan, Simon Randall, Fabrizio Ortu, Alan M. Kenwright, Louise S. Natrajan

Publikováno v: Inorganics, Vol 4, Iss 3, p 27 (2016)

The construction of lanthanide(III) chelates that exhibit superior photophysical properties holds great importance in biological and materials science. One strategy to increase the luminescence properties of lanthanide(III) chelates is to hinder comp

Externí odkaz: https://doaj.org/article/cd0ff5f033b4420b8cc744aa5174db72

Separating the coherence transfer from chemical shift evolution in high-resolution pure shift COSY NMR

Autor: Juan A. Aguilar, Ilya Kuprov, Raquel Belda, Benjamin R. Gaunt, Alan M. Kenwright

Publikováno v: Magnetic resonance in chemistry, 2018, Vol.56(10), pp.969-975 [Peer Reviewed Journal]

Recent developments in data sampling and processing techniques have made it possible to acquire two-dimensional NMR spectra of small molecules at digital resolutions in both dimensions approaching the intrinsic limitations of the equipment and sample

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::2a6de166c984947fbaa4d6358c5459dc
https://doi.org/10.1002/mrc.4727

Fluoride Binding and Crystal-Field Analysis of Lanthanide Complexes of Tetrapicolyl-Appended Cyclen

Autor: Jose M. Goicoechea, Stephen Faulkner, Andrew R. Jupp, Octavia A. Blackburn, Paul D. Beer, Alan M. Kenwright

Publikováno v: Chemistry - A European Journal. 22:8929-8936

Lanthanide complexes of tetrapicolyl cyclen displayed remarkably high affinities for fluoride (log K≈5) in water, and were shown to form 1:1 complexes. The behaviour of these systems can be rationalised by changes to the magnitude of the crystal-fi

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::8a1629d1f736086aecc81ccc94d2ddaf
https://doi.org/10.1002/chem.201601170