Zobrazeno 1 - 10
of 47
pro vyhledávání: '"A. Gonthier-Vassal"'
Autor:
Anne Gonthier-Vassal, Henri Szwarc
Publikováno v:
Thermochimica Acta. 320:141-154
In this paper, we describe the study of the thermodynamic properties of all cycloketones, from cyclobutanone to cyclododecanone, through DSC measurements in order to reveal possible new glassy crystalline phases. This work presents revised phase diag
Autor:
Anne Gonthier-Vassal, H. Szwarc, René Céolin, Viatcheslav N. Agafonov, Siro Toscani, M. F. Gardette
Publikováno v:
Fullerene Science and Technology. 5:559-565
By slowly evaporating at room temperature solutions of C60 in n-octane, crystals of the hexagonal solvate C60 1 n-octane have been obtained (a = 10.10, c = 10.18 A)., Although these crystals are formed with a negative volume excess of − 24 A3 per f
Autor:
Henri Szwarc, René Céolin, Ph. Ladure, J. M. Cense, Anne Gonthier-Vassal, Viatcheslav N. Agafonov
Publikováno v:
Journal of Thermal Analysis. 45:1277-1284
Flutamide usually crystallizes in the orthorhombic non-centrosymmetric space group Pna21 (from I) and melts atT fus =384 K with Δfus H=30 kJ·mol−1. It may be obtained in the glassy state (T g =272 K) by quenching the melt. Although evidence of po
Autor:
V. N. Agafonov, Siro Toscani, René Céolin, Henri Szwarc, G. Keller, Anne Gonthier-Vassal, Claude Fabre, André Rassat, Bernard Bachet
Publikováno v:
Chemical Physics Letters. 244:100-104
Crystallographic and thermodynamic experiments show that crystalline C60 obtained by slow evaporation of solutions in n-heptane is a C60, n-heptane 1:1 solvate. Its lattice is hexagonal, Laue class 6/mmm, with a = 10.00(4) A and c = 10.16(1) A. No tr
Publikováno v:
Solid State Ionics. 74:239-248
We have investigated structural transitions in Pr 2 NiO 4+δ(δ≥0) using DSC, TGA and XRD measurements. This study reveals firstly that the so called LTT (Low Temperature Tetragonal) phase i.e. P4 2 /ncm symmetry exists not only for δ=0 but also f
Autor:
Philippe E. Raison, P. J. Brown, A. Gonthier-Vassal, B. Kanellakopulos, J. M. Kiat, P. Schweiss, G. H. Lander, Christos Apostolidis, Jean Rebizant, A. Delapalme
Publikováno v:
Zeitschrift für Kristallographie - Crystalline Materials. 209:720-726
We have used neutron and X-ray diffraction techniques on both single crystal and polycrystalline samples to examine the symmetry of the unit cell of the organometallic compound uranium tris(cyclopentadienyl)chlorine, U(C5H5)3Cl, as a function of temp
Autor:
Nicole Ratovelomanana, Daniel André, Henri Szwarc, Frédéric Dunstetter, Anne Gonthier-Vassal, M.F. Lautie
Publikováno v:
Chemical Physics. 175:475-482
Deuterated thiophene has been studied by powder neutron diffraction spectroscopy from ∼ 60 K to melting temperature. Preliminary DSC measurements have shown that the thermodynamic behaviours of hydrogenated and deuterated thiophene are almost ident
Autor:
Jeroen de Bruijn, Henri Szwarc, Anne Gonthier-Vassal, Daniel André, André Rassat, Virginie Greugny, Siro Toscani, René Céolin, Viatcheslav N. Agafonov, Jérôme Dugué, Claude Fabre, Noël Rodier, Pierre-Yves Sizaret
Publikováno v:
Chemical Physics Letters. 208:68-72
X-ray diffraction and thermodynamic measurements show that crystalline fullerene C70 obtained from toluene solutions is a C70, toluene 1:1 solvate. Its structure is orthorhombic with space group Pbca (a = 21.075 A, b = 32.990 A, c = 10.844 A). The ev
Publikováno v:
Journal of Labelled Compounds and Radiopharmaceuticals. 33:39-43
Cyano-[D11]-cyclohexane was prepared from commercial [D12]-cyclohexanol via the sequence alcohol-chloride-acid-nitrile in an overall yield of 33% after purification. Isotopic purity was at least 98%.
Publikováno v:
Thermochimica Acta. 202:87-96
By means of a DSC study, 2-bromothiophene was shown to possess three different phases which melt at atmospheric pressure. These phases, the existence of which was subsequently checked by Raman spectroscopy, were obtained reproducibly through simple t