Zobrazeno 1 - 10
of 14
pro vyhledávání: '"A. G. Whitehurst"'
Publikováno v:
Journal of the American Chemical Society
Five- and six-coordinate cationic bis(phosphine) cobalt(III) metallacycle complexes were synthesized with the general structures, [(depe)Co(cycloneophyl)(L)(L′)][BArF4] (depe = 1,2-bis(diethylphosphino)ethane; cycloneophyl = [κ-C:C-(CH2C(Me)2)C6H4
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::c43066ead6acef4ae8a9ce7abb3668ae
https://pubmed.ncbi.nlm.nih.gov/36194198
https://pubmed.ncbi.nlm.nih.gov/36194198
Publikováno v:
Journal of the American Chemical Society
A cobalt-catalyzed intermolecular three-component coupling of arenes, ethylene, and alkynes was developed using the well-defined air-stable cationic bis(phosphine) cobalt(I) complex, [(dcype)Co(η6-C7H8)][BArF4] (dcype = 1,2-bis(dicyclohexylphosphino
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::651a216c539d3de5c813239f89b22c9b
https://pubmed.ncbi.nlm.nih.gov/35245039
https://pubmed.ncbi.nlm.nih.gov/35245039
Publikováno v:
Journal of the American Chemical Society. 142:14169-14177
Alkyl Pd(IV) complexes are frequently invoked in the proposed mechanisms of Pd-catalyzed C(sp3)–H functionalization reactions, though few examples of Pd(IV) complexes containing cyclopalladated sub...
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::0bff1502da9db8873c55f0ec167b87cf
https://doi.org/10.1021/jacs.0c04732
https://doi.org/10.1021/jacs.0c04732
Publikováno v:
Nature
The ubiquity of tertiary alkylamines in pharmaceutical and agrochemical agents, natural products and small-molecule biological probes1,2 has stimulated efforts towards their streamlined synthesis3–9. Arguably the most robust method for the synthesi
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::0d4bc10af2f35211225d45c51130f9a0
https://doi.org/10.1038/s41586-020-2213-0
https://doi.org/10.1038/s41586-020-2213-0
Publikováno v:
Angewandte Chemie. 131:9152-9157
Reported is the discovery of an approach to functionalize secondary alkylamines using 2-halobenzoic acids as aryl-transfer reagents. These reagents promote an unusually mild carboxylate-assisted oxidative addition to alkylamine-derived palladacycles.
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::291bc4371aa999a1f13afbe7d8f76e9d
https://doi.org/10.1002/ange.201902838
https://doi.org/10.1002/ange.201902838
Publikováno v:
Chem. 5:1031-1058
Methods that enable the practical and selective functionalization of traditionally unreactive aliphatic C–H bonds have synthetic applications in fields ranging from drug discovery to advanced materials. One of the major challenges is the developmen
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::dd5c71fa4590f5d8b04abdd3b032e1be
https://doi.org/10.1016/j.chempr.2018.12.017
https://doi.org/10.1016/j.chempr.2018.12.017
Publikováno v:
Angewandte Chemie. 130:3232-3236
A palladium(II)-catalyzed γ-C-H amination of cyclic alkyl amines to deliver highly substituted azetidines is reported. The use of a benziodoxole tosylate oxidant in combination with AgOAc was found to be crucial for controlling a selective reductive
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::3d111b4f42844fde8c31a67972839c95
https://doi.org/10.1002/ange.201800519
https://doi.org/10.1002/ange.201800519
We report a practical and general solution to this long-standing synthetic challenge can be accomplished by addition of alkyl radicals to all alkyl-iminium ions. The process is mediated by the action of visible light and a simple silane reducing agen
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::a4766a813a874a578a8881a640331e82
https://doi.org/10.26434/chemrxiv.10028504
https://doi.org/10.26434/chemrxiv.10028504
Publikováno v:
Angewandte Chemie (International ed. in English). 57(12)
A palladium(II)-catalyzed γ-C-H amination of cyclic alkyl amines to deliver highly substituted azetidines is reported. The use of a benziodoxole tosylate oxidant in combination with AgOAc was found to be crucial for controlling a selective reductive
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=pmid________::dc36b6fca645f8885d9b43cbdef772c9
https://pubmed.ncbi.nlm.nih.gov/29380496
https://pubmed.ncbi.nlm.nih.gov/29380496
Autor:
H. Leigh-Firbank, Leonid M. Gelman, Radoslaw Zimroz, B. Waterland, J. Birkel, G. Whitehurst, Daniel M. Simms
Publikováno v:
Noise & Vibration Worldwide. 37:19-25
An adaptive approach was applied for local tooth damage diagnostics in gearboxes. The expediency of adaptation was proved experimentally for the new diagnostic feature, the sum of normalized sideband amplitudes. The positive correlation between mesh
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::5d7cfde5d04aed61ad290271ddf352f6
https://doi.org/10.1260/095745606776318204
https://doi.org/10.1260/095745606776318204