Zobrazeno 1 - 8
of 8
pro vyhledávání: '"A. G. Rebrova"'
Publikováno v:
Russian Journal of Applied Chemistry. 90:113-119
The kinetics of leaching of Karelian shungites (types I–III) with water at pH in the interval 1–12 was studied. Changes in the chemical composition and structure of the shungite substance were revealed by X-ray fluorescence analysis and scanning
Publikováno v:
Russian Journal of Applied Chemistry. 85:396-400
Complexing capacity of carboxyethyldextranhydroxamic acid with respect to the metal cations Fe3+, Cu2+, Ni2+, Co2+, and Mn2+ was studied. A procedure for synthesis of the complexes being formed was suggested and the compounds obtained were analyzed b
Publikováno v:
Kinetics and Catalysis. 51:485-491
From recent rate constant data for the recombination reaction 2CF 3 • → C2F6 ( % MathType!MTEF!2!1!+- % feaagaart1ev2aaatCvAUfeBSjuyZL2yd9gzLbvyNv2CaerbuLwBLn % hiov2DGi1BTfMBaeXatLxBI9gBaerbd9wDYLwzYbItLDharqqr1ngB % PrgifHhDYfgasaacH8WrFz0dbbf9
Publikováno v:
Russian Journal of General Chemistry. 79:2641-2651
The fact was established that the pyrolysis of gaseous iodomethanes RI yields methane and non traces of recombination products R2. A pyrolysis mechanism was proposed and rate constants of limiting stages of the pyrolysis of iodomethane, trideuteroiod
Publikováno v:
Kinetics and Catalysis. 49:466-473
The rate constant of CF 3 · recombination ( $$ k_{(CF_3 )_2 }^M $$ ) in the isochoric isothermal pyrolysis of trifluoroiodomethane at T = 625–732 K and P = 29–300 Torr was derived from molecular iodine accumulation curves. Using literature data
Publikováno v:
Russian Journal of General Chemistry. 76:245-250
Molecular parameters and thermodynamic functions of the carbon cluster cyclo-C12 were calculated by the B3LYP method in the aug-cc-pVDZ basis. The composition of products of iodomethane pyrolysis in the range 500–1000 K was calculated from the data
Publikováno v:
Russian Journal of General Chemistry. 75:1524-1536
The limiting step of the isothermal pyrolysis of gaseous iodomethane (CH3I → 3/4CH4 + 1/2I2 + 1/(4n)C n ) and diiodomethane (CH2I2 → 1/2CH4 + I2 + 1/(2n)C n ) are the reactions 2CHI → C2 + 2HI and 2CI2 → C2 + 2I2, respectively. The rate const
Publikováno v:
Russian Journal of General Chemistry. 75:1411-1420
Final products of isothermal pyrolysis of CF2HBr, CF2ClBr, CH3I, CH2I2, CHI3, i-C3F7I, and C4F9I were determined and mechanisms of their formation were proposed. The enthalpy of formation of the free biradical CFBr·· (Δf H 0 0 = 80±20, Δ f H 0 2