Zobrazeno 1 - 10
of 256
pro vyhledávání: '"A. G. AVENT"'
Autor:
David W. H. Rankin, Anthony G. Avent, Paul D. Lickiss, Derek A. Wann, Stuart Young, Sarah L. Masters, Karin Bätz
Publikováno v:
Zeitschrift für Naturforschung B. 69:1321-1332
The structures of the molecules C(SiXMe2)4 (X=H, F, Cl, Br) have been determined by gas electron diffraction (GED). Ab initio calculations revealed nine potential minima for each species, with significant ranges of energies. For the H, F, Cl, and Br
Publikováno v:
Journal of Organometallic Chemistry. 689:3513-3519
The reactions of [HIr4(CO)9(Ph2PC CPh)(μ-PPh2)] (1) or [Ir4(CO)8(μ3-η2-HCCPh)(μ-PPh2)2] (2) with HC CPh gave two isomeric forms of [Ir4(CO)6(μ3-η2-HCCPh)(μ2-η4-C4H2Ph2)(μ-PPh2)2] (3 and 4) in good yields as the only products. These compounds
Autor:
Lewis E. Pennicott, Rupert O. Sims, Clive S. Penkett, Simon Berritt, Paul W. Byrne, Stephen P.G. Rushton, Anthony G. Avent, Peter B. Hitchcock
Publikováno v:
Tetrahedron. 62:9403-9409
Whilst seeking to improve the yield of a Heck-style arylation/fragmentation reaction using a silyloxy substituted meta photocycloadduct, an alternative reaction pathway was discovered that led to the formation of the unique oxidatively cyclised compo
Publikováno v:
Journal of Chemical Research. 2006:580-583
The vinylogous thiazine urethanes 1 are invariably acylated on carbon and not on nitrogen, even when the carbon is “blocked” as in 18. The analogous thiazolidine 2 is acylated either on carbon or nitrogen, depending on the electrophile used.
Publikováno v:
Organometallics. 25:2470-2474
Multinuclear NMR spectroscopy and X-ray diffraction techniques have been used to identify diastereomeric mixtures of rac- and meso-di(phosphaguanidine) compounds. A brief survey of their coordination chemistry has demonstrated the formation of N,N'-b
Autor:
Anthony G. Avent, Lee P. Kingston, Rupert O. Sims, Peter B. Hitchcock, Jason Lai, Simon Berritt, Clive S. Penkett, Richard French, Lauriane Dray, Paul W. Byrne
Publikováno v:
Tetrahedron. 62:3423-3434
Substituted benzene derived meta photocycloadducts have been shown to undergo a fragmentation/arylation reaction under Heck reaction conditions to give bridged bicyclo[3.2.1] compounds in a highly atom-efficient manner. When an anisole derived meta p
Publikováno v:
Journal of Organometallic Chemistry. 691:1242-1250
A series of heteroleptic calcium eta(5)-C5R5 cyclopentadienides supported by an N-Dipp (Dipp = 2,6-(Pr2C6H3)-Pr-i)-substituted beta-diketiminate ligand have been synthesised by selective protonolysis of the readily available reagent [HC{(C(Me)N(Dipp)
Autor:
Peter B. Hitchcock, Anthony G. Avent, Floria Antolini, Michael F. Lappert, Andrey V. Protchenko, Alexei V. Khvostov
Publikováno v:
Dalton Trans.. :919-927
Reactions between sodium amides Na[N(SiMe3)R1] [R1 = SiMe3 (1), SiMe2Ph (2) or But (3)] and cyanoalkanes RCN (R = Ad or But) were investigated. In each case the nitrile adduct [Na{mu-N(SiMe3)2}(NCR)]2 [R = Ad (1a) or But (1b)], trans-[Na{mu-N(SiMe3)(
Autor:
Alaa Abdul-Sada, Pavel A. Troshin, Roger Taylor, Natalia Martsinovich, Joan M. Street, A. G. Avent, A. D. Darwish
Publikováno v:
Science. 309:278-281
Fluorination of C 60 at 550°C leads to milligram quantities of two stable fullerene derivatives with 58-carbon cage structures: C 58 F 18 and C 58 F 17 CF 3 . The compounds were characterized by mass spectrometry and fluorine nuclear magnetic resona
Publikováno v:
Organometallics. 24:1184-1188
The "selective" protonolysis of the beta-diketiminato calcium derivative [Ca{(NDippCMe)(2)CH}{N(Si-Me-3)(2)}(THF)] (Dipp = (C6H3Pr2)-Pr-i-2,6) with a selection of terminal alkynes has produced a series of dimeric acetylides [Ca{(NDippCMe)(2)CH}{mu-C