Zobrazeno 1 - 10
of 13
pro vyhledávání: '"A. F. Efremkin"'
Publikováno v:
Russian Journal of Physical Chemistry B. 14:522-524
The results of kinetic studies of the recombination of radicals in the cage and in bulk of polymers obtained by nanosecond laser photolysis are summarized. The films of rubbers (poly(ethylene-co-butylene)), biaxially oriented polypropylene depending
Publikováno v:
Chemical Physics. 495:23-28
The review article is devoted to kinetics of fast reactions following photoexcitation of benzophenone in polymer films. We observed three processes by ns laser flash photolysis in elastomers: (i) decay of a triple state of benzophenone with hydrogen
Autor:
Igor V. Khudyakov, O. V. Shatalova, Peter P. Levin, A. V. Krivandin, Alexei F. Efremkin, Sergei Michael Lomakin
Publikováno v:
The journal of physical chemistry. A. 122(17)
The photoinduced reactions of benzophenone (B) in biaxially oriented polypropylene (BOPP) were studied with nanosecond laser photolysis (N2 laser, λ337.1 nm). The first observed transient was a triplet state 3B*. Decay of 3B* led to formation of a r
Publikováno v:
Coatings, Vol 9, Iss 2, p 111 (2019)
Photoinduced elementary reactions of low-MW compounds in polymers is an area of active research. Cured organic polymer coatings often undergo photodegradation by free-radical paths. Besides practical importance, such studies teach how the polymer env
Autor:
A. V. Petryaykin, T. A. Akhadov, Irina Lebedeva, A. F. Efremkin, A. S. Tyurneva, N. A. Semenova, Kaleda Vg, M. V. Ublinskiy
Publikováno v:
Doklady Biochemistry and Biophysics. 453:288-291
Publikováno v:
Photochemistry and Photobiology. 90:369-373
The kinetics of transients formed under photoexcitation of benzophenone (B) dissolved in three different polymers was studied by ns laser flash photolysis. These polymers were the soft rubbers poly (ethylene-co-butylene) (EB), polystyrene block-poly(
Publikováno v:
The journal of physical chemistry. A. 120(38)
The effect of polymer film elongation leading to the thinning of the film up to three times on the decay of transients was studied. Kinetics of benzophenone (B) triplet state (3)B* and ketyl free radical BH• in soft rubber poly(ethylene-co-butylene
Publikováno v:
Russian Journal of Inorganic Chemistry. 56:252-257
The vanadyl ionic complex VO(DMSO)5(ClO4)2 (I) exhibits high catalytic activity in the polymerization of 2-hydroxyethyl methacrylate (HEMA). The changes in the vanadium oxidation state during polymerization under argon and in the presence of oxygen w
Publikováno v:
Photochemicalphotobiological sciences : Official journal of the European Photochemistry Association and the European Society for Photobiology. 14(5)
The decay kinetics of intermediates produced under photolysis of benzophenone (B) dissolved in soft rubber poly(ethylene-co-butylene) films (abbreviated as E) was studied by ns laser flash photolysis in the temperature range of 263-313 K. We monitore
Autor:
V. B. Ivanov, A. F. Efremkin
Publikováno v:
Russian Chemical Bulletin. 45:1350-1352
The formation of 4-plienylaminopltenyldiplienylcarbinol and related triarylrnethne dye was observed upon the recombination of keyl and diphenylaminc radicals in surfactant micelles. The negative magnetic effect of the reaction studied reaches 1.8 and