Zobrazeno 1 - 10
of 117
pro vyhledávání: '"A. C. Lasaga"'
Publikováno v:
Chemical Geology. 249:357-376
Ab initio calculations of vibrational frequencies ( ν ), reduced partition function ratios ( β ) of various gaseous and aqueous sulfur-bearing compounds, and isotopic fractionation factors ( α ) between them were performed on the multiple isotope
Publikováno v:
Earth and Planetary Science Letters. 268:225-238
Applying square adsorption-well and Morse potential models for the adsorption of a sulfur specie on a solid surface, we have evaluated the fractionation of four sulfur isotopes (32S, 33S, 34S and 36S) during chemisorption reactions. Heterogeneous rea
Autor:
Antonio C. Lasaga, Andreas Luttge
Publikováno v:
The Journal of Physical Chemistry B. 109:1635-1642
Using a simple, feldspar-like model and the crystal-based reaction mechanism for water-rock kinetics being developed before, we show directly how the dissolution of euhedral faces of crystals are governed by the nonlinear quantity represented by the
Autor:
Andreas Luttge, Antonio C. Lasaga
Publikováno v:
European Journal of Mineralogy. 16:713-729
Incorporating mineral structures and interpreting the wide array of water-rock kinetic field and experimental data, requires abandoning molecule-based adsorption phenomenological models and the development and analysis of a general kinetic theory tha
Autor:
Antonio C. Lasaga, Andreas Luttge
Publikováno v:
American Mineralogist. 89:527-540
We introduce a general kinetic model for crystal dissolution that explicitly tracks all the various atoms in the crystal structure as part of the reaction mechanism. This model will be used in this and subsequent articles to develop a theory for the
Autor:
Antonio C. Lasaga, Andreas Luttge
Publikováno v:
European Journal of Mineralogy. 15:603-615
A comprehensive dissolution rate theory that integrates individual surface reactions into an overall rate is developed. The dissolution theory is based on the movement of dissolution stepwaves stemming from surface defects. The net bulk rate associat
Publikováno v:
Geochimica et Cosmochimica Acta. 67:1099-1116
The dissolution rate and mechanism of three different cleavage faces of a dolomite crystal from Navarra (near Pamplona), Spain, were studied in detail by vertical scanning interferometry techniques. A total of 37 different regions (each about 124 ×
Autor:
Antonio C. Lasaga, Hiroshi Ohmoto
Publikováno v:
Geochimica et Cosmochimica Acta. 66:361-381
The first and possibly only major rise of atmospheric oxygen, from p O 2 ≤ 0.1% PAL (the present atmospheric level) to p O 2 ≥ 10% PAL, appears to have occurred sometime before 2 Ga ago, although the exact time of and the cause(s) for the rise ha
Publikováno v:
Geochimica et Cosmochimica Acta. 65:1161-1185
The movement of fluids in the crust and upper mantle not only lead to important mineral reactions but also play an essential role in the geochemical cycling of elements and in controlling global change. Numerous papers have focused on calculation of