Zobrazeno 1 - 10
of 42
pro vyhledávání: '"A. Choualeb"'
Autor:
Dmitry G. Gusev, Aldjia Choualeb, Brandon D. Moore, Denis Spasyuk, Marcello Bertoli, Alan J. Lough
Publikováno v:
Organometallics. 30:3479-3482
A series of pincer-type complexes of Os and Ru have been synthesized and investigated in catalytic alcohol dehydrogenation. The hydrides OsHCl(CO)[HN(C2H4PiPr2)2] and OsH2(CO)[HN(C2H4PiPr2)2] possess good air, moisture, and thermal stability and are
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::63ede8c2807e9068b8a796b699d5171a
https://doi.org/10.1021/om200437n
https://doi.org/10.1021/om200437n
Autor:
Aldjia Choualeb, Heinz Berke, Olivier Blacque, Helmut W. Schmalle, Thomas Hiltebrand, Thomas Fox
Publikováno v:
European Journal of Inorganic Chemistry. 2007:5246-5261
Replacement of the MeCN group in the acetonitrile-cis-dibromo(nitrosyl)-trans-bis(phosphane)rhenium compounds la,b (R = iPr a, R = Cy b) with ethylene afforded the olefin derivatives [Re(η 2 -H 2 C=CH 2 )(NO)(PR 3 ) 2 Br 2 ] (2a,b) (R = iPr a, R = C
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::63437c43cec898772f2cbbf71901cfb7
https://doi.org/10.1002/ejic.200700573
https://doi.org/10.1002/ejic.200700573
Publikováno v:
Organometallics. 26:5224-5229
The ligand tBu2PC2H4NHC2H4NEt2 (PNHN) was synthesized starting from 2-(diethylamino)ethyl chloride hydrochloride and ethanolamine. Reaction of PNHN with [IrCl(COE)2]2 under H2 afforded the dihydride cis-IrH2Cl(κ3-PNHN) (1) in excellent yield. Treatm
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::fe5cf39610546cbbfed1ab0f62317284
https://doi.org/10.1021/om700550x
https://doi.org/10.1021/om700550x
Publikováno v:
Organometallics. 26:3509-3515
The hydride complexes ReHBr(NO)[HN(C2H4PR2)2] (R = Pri, 1a; But, 1b) were synthesized by reactions of [NEt4]2[Re(NO)Br5] with the pincer-type ligands HN(C2H4PR2)2. Treatment of 1a and 1b with ButOK led to their dehydrobromination, resulting in the am
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::da5381ece73e520e8bfd93bc6a16de56
https://doi.org/10.1021/om070206+
https://doi.org/10.1021/om070206+
Publikováno v:
Organometallics. 22:4405-4417
Short-bite ligand cluster stabilization is achieved in the tetrahedral clusters [Co4(μ-CO)3 (CO)7(μ-dppy)] (1a−c), obtained in high yields by reactions of [Co4(CO)12] with 1 equiv of the diphosphine ligands dppy, Ph2PCH2PPh2 (dppm), Ph2PNHPPh2 (d
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::5ffa6ccd9c4e0bae3d5b9d677f0f2dc0
https://doi.org/10.1021/om030327j
https://doi.org/10.1021/om030327j
Publikováno v:
Organometallics. 22:2688-2693
Two general approaches are presented and compared to covalently link metal clusters to alkynes terminated with a trialkoxysilyl or a thioether group. They consist in the direct reaction of the functional alkyne with the cluster or in the functionaliz
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::50e81f873eb2676ddd02315a3a0d6f95
https://doi.org/10.1021/om020965m
https://doi.org/10.1021/om020965m
The tris(acetonitrile)dibromonitrosylrhenium(I) compound (1a) was obtained by reduction of the paramagnetic [NMe4]2[Re(NO)Br5] salt with Zn in MeCN. Subsequent reaction of 1a with THF produced the THF derivative [Re(NO)(THF)(MeCN)2Br2] (1b). Reaction
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::193be980d8371c7136342d6b12198f47
https://doi.org/10.5167/uzh-13273
https://doi.org/10.5167/uzh-13273
Publikováno v:
Inorganic chemistry. 43(1)
The tetrahedral cluster [RuCo(3)(CO)(12)](-) reacts with various alkynes, including the new PhCtbd1;CC(O)NHCH(2)Ctbd1;CH (L(1)()), to afford the butterfly clusters [RuCo(3)(CO)(10)(micro(4)-eta(2)-RC(2)R')](-) (1, R = R' = C(O)OMe; 2, R = H, R' = Ph;
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::5f7378ea38578b14a6f577478650f8f3
https://pubmed.ncbi.nlm.nih.gov/14704054
https://pubmed.ncbi.nlm.nih.gov/14704054
Autor:
Brandon D. Moore, Marcello Bertoli, Dmitry G. Gusev, Quinn Major, Aldjia Choualeb, Alan J. Lough
Publikováno v:
Dalton Transactions. 40:8941
This paper reports the synthesis, structure, and properties of a series of PNP pincer complexes of osmium OsH(3)Cl[HN(C(2)H(4)P(i)Pr(2))(2)] (1), OsH(3)[N(C(2)H(4)P(i)Pr(2))(2)] (2), OsH(4)[HN(C(2)H(4)P(i)Pr(2))(2)] (3), and OsH(2)(PMe(3))[HN(C(2)H(4
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::a31adeb5f3ca4728a83825b32b90fbfd
https://doi.org/10.1039/c1dt10342c
https://doi.org/10.1039/c1dt10342c
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