Zobrazeno 1 - 10
of 75
pro vyhledávání: '"A I Shatenshtein"'
Publikováno v:
Journal of Polymer Science Part C: Polymer Symposia. 16:1729-1737
The anion polymerization process is affected by the solvent and the counterion. A study has been made of the quantitative aspects of this effect using as a model reaction the formation of aromatic anion radicals in various ethers. The solvating capac
Autor:
E. N. Tsvetkov, T. M. Shcherbina, N. G. Osipenko, M. I. Kabachnik, Yu. I. Ranneva, A. I. Shatenshtein, E. S. Petrov
Publikováno v:
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 26:1448-1452
1. In order to explain the effect structure of the solvating properties of phosphine oxides, a series of phosphine oxides containing ether, amine, and aminoether groups was synthesized. 2. A series of methyldi(methoxymethyl)phosphine oxide analogs co
Publikováno v:
Chemistry of Heterocyclic Compounds. 15:904-908
Autor:
S. P. Mesyats, M. I. Kabachnik, E. N. Tsvetkov, R. A. Malevannaya, M. I. Terekhova, A. I. Shatenshtein, E. S. Petrov
Publikováno v:
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 27:1743-1746
1. The transmetallation method has been used to measure equilibrium acidities of P(O)H-and P(S)H-acids of various structures in dimethylsulfoxide solution and relative to 9-phenyl-fluorene. 2. The effect of the substituent at the P atom on the pK val
Publikováno v:
Theoretical and Experimental Chemistry. 22:425-430
Bronsted relations with anomalous (less than zero) values for the α coefficient were obtained for the ionization reactions of monoalkylpyridines, monoalkylbiphenyls, and monoalkylbenzenes in solutions of the lithium (or potassium) tertbutoxide and d
Autor:
A. N. Vasil'ev, N. I. Golovanova, E. S. Petrov, S. E. Korostova, M. I. Terekhova, Al'bina I. Mikhaleva, Boris A. Trofimov, A. I. Shatenshtein
Publikováno v:
Chemistry of Heterocyclic Compounds. 16:488-495
The pK values of a series of substituted pyrroles and the ΔvNH values (in dimethylformamide), which characterize their relative acidities were measured by the transmetallation method. It was established that the acidities of pyrroles are determined
Publikováno v:
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 30:993-997
1. The equilibrium NH acidities of benzenesulfonamide and its derivatives have been studied by the transmetallation method in DMSO. 2. Linear relationships connecting the pK values of benzenesulfonamides C6H5SO2NHR with the σ* constants of alkyl gro
Autor:
T. V. Sakhno, A. I. Shatenshtein, E. S. Petrov, G. A. Val'kova, N. N. Voinovskaya, L. F. Rybakova, M. I. Terekhova
Publikováno v:
Chemistry of Heterocyclic Compounds. 18:957-960
The equilibrium NH acidities of acridan, phenanthridone, 9-acridone, and 2-substituted 9-acridones (substituents: Me2N, MeO, F, Br, I, and NO2) were measured by transmetallation in dimethyl sulfoxide (DMSO). The role of conjugation and the aromatic c
Autor:
S. P. Mesyats, S. Petrov, E. N. Tsvetkov, M. I. Terekhova, M. I. Kabachnik, A. I. Shatenshtein
Publikováno v:
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 23:2399-2405
Among organophosphorus earbanions , the bas ic i ty only of phosphonium-conta ining ca rban ions (phosphinomethylenes) has been quant i ta t ively studied [1]. E a r l i e r we were the f i r s t to ci te data on the CHacidi ty (pK)* of ce r ta in ph
Autor:
T. M. Shcherbina, E. S. Petrov, N. N. Shelganova, A. I. Shatenshtein, S. P. Mesyats, M. I. Kabachnik, E. N. Tsvetkov
Publikováno v:
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 23:2406-2412
1. The equilibrium CH-acidity (pK) of benzylphosphine oxides, as well as esters and tetraalkyl-amides of benzylphosphonic acid in diglyme (DG) and DMSO was determined by the method of transmetallation. 2. The acidity in DMSO is 4–6 units of pK lowe