Isomerization and aggregation of 2-(2-(2-hydroxy-4-nitrophenyl)hydrazono)-1-phenylbutane-1,3-dione: Recent evidences from theory and experiment

Autor: Aurélien Crochet, Poul Erik Hansen, Liudmil Antonov, Fadhil S. Kamounah, Katharina M. Fromm, Silvia Hristova, Daniela Nedeltcheva

Publikováno v: Hristova, S, Kamounah, F S, Crochet, A, Hansen, P E, Fromm, K M, Nedeltcheva, D & Antonov, L 2019, ' Isomerization and aggregation of 2-(2-(2-hydroxy-4-nitrophenyl)hydrazono)-1-phenylbutane-1,3-dione : Recent evidences from theory and experiment ', Journal of Molecular Liquids, vol. 283, pp. 242-248 . https://doi.org/10.1016/j.molliq.2019.03.073

The title compound potentially can exist as four isomers in solution. Recently Lycka has proposed a protocol for distinguishing two of them based on 15N NMR. This approach has been confirmed theoretically, in the current study, and further developed

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::71a5c9e6fad01de1ebe747c07d9a37af
http://doc.rero.ch/record/326728/files/fro_iaa.pdf

Theoretical calculations on the mechanisms of the gas-phase elimination kinetics of 2-chloro-1-phenylethane, 3-chloro-1-phenylpropane, 4-chloro-1-phenylbutane, 5-chloro-1-phenylpentane, and their corresponding chloroalkanes: The effect of the phenyl ring

Autor: Gabriel Chuchani, Tania Cordova, Simon J. Subero, José R. Mora, Marcos Loroño, Alexis Maldonado

Publikováno v: International Journal of Chemical Kinetics. 43:292-302

The kinetics and mechanisms of the dehydrochlorination of 2-chloro-1- phenylethane, 3-chloro-1-phenylpropane, 4-chloro-1-phenylbutane, 5-chloro-1-phenylpentane, and their corresponding chloroalkanes were examined by means of electronic structure calc

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::3c16409d98402b37844dae2df6e04114
https://doi.org/10.1002/kin.20548

Copper(II) and 2,2′-Biimidazole-promoted Novel Reaction of 4,4,4-Trifluoro-1-phenylbutane-1,3-diones with Iodobenzene Diacetate

Autor: Chunmei Zhou, Runsheng Zeng, Jian-Ping Zou

Publikováno v: Chinese Journal of Chemistry. 28:294-298

A new and efficient way was developed to carry out the reaction of 4,4,4-trifluoro-1-phenylbutane-1,3-dione with iodobenzene diacetate under the assistance of Cu(II) and 2,2′-biimidazole at a low temperature in excellent yield. 2-Acetoxyacetophenon

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::3f4f5150762764c9a90e80d33de2110b
https://doi.org/10.1002/cjoc.201090069

Crystal structure of 2-(bis(methylthio)methylene)-1-phenylbutane-1,3-dione, C13H14O2S2

Autor: Assem Barakat, Wolfgang Frey, Saied M. Soliman, Yahia N. Mabkhot, Salim S. Al-Showiman, Hazem A. Ghabbour

Publikováno v: Zeitschrift für Kristallographie-New Crystal Structures, Vol 231, Iss 2, Pp 473-474 (2016)

C13H14O2S2, triclinic, P1̅ (no. 2) a = 8.0970(9) Å, b = 8.8152(10) Å, c = 9.8217(10) Å, α = 76.269(5)°, β = 69.539(4)°, γ = 82.065(5)°, ϛ = 636.87(12) Å3, Z = 2, R gt (F) = 0.028, wR ref (F 2 ) = 0.073, T = 100 K.

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::b618b3dce2f738a830658ccc02f8644f
https://doi.org/10.1515/ncrs-2015-0144

Trifluoromethylated 1,2λ5σ4-oxaphospholanes via λ5σ5P tricyclic phosphoranes from 4,4,4-trifluoro-3-hydroxy-1-phenylbutane-1-one and dichlorophosphines. Molecular structure of a trapped phosphonite

Autor: Kazimir I. Pashkevich, Enno Lork, V. G. Ratner, Gerd-Volker Röschenthaler

Publikováno v: Journal of Fluorine Chemistry. 85:129-133

Reacting 4,4,4-trifluoro-3-hydroxy-1-phenylbutane-1-one (1) with the dichlorophosphines RPCl 2 ( 2a , R = Me; 2b , R = Ph) gave the phosphonites 3a and 3b , which, in the case of 3a , was trapped using hexaHuoroacetone to furnish the 1,3,2λ 5 σ 5 -

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::2685a273cc982bd4639844160155514f
https://doi.org/10.1016/s0022-1139(97)00061-4