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Autor:
and Yuh S. Wen, Mei M. Chen, Shiow Y. Wang, ‡ Chih Ch'ing Yu, Kuan J. Lin, Jiann T. Lin, ‡ Ch'i Hsing Lo, Thamas Y. R. Tsai
Publikováno v:
Organometallics. 15:2132-2136
Treatment of [NMe4]3[M3(CO)9(μ-OEt)(μ3-OEt)2] (1, M = Mo; 2, M = W) with 3 equiv of (Ph3P)AuCl/TlPF6 affords M3(CO)9(AuPPh3)3(μ-OEt)(μ3-OEt)2 (3, M = Mo; 4, M = W) in 80% and 89% yields, respectively. The molecular structures of 3 and 4 have been