Zobrazeno 1 - 10
of 24
pro vyhledávání: '"Štěpán Vyskočil"'
Autor:
Ahmed F. Abdel-Magid, Jaan A. Pesti, Rajappa Vaidyanathan, Hirotaki Mizutani, Steven Langston, Stepan Vyskocil, Ian Armitage, Ashley McCarron, Lei Zhu, Ian M. Bell, Paul G. Bulger, Mark McLaughlin, Jason S. Tedrow, Wenge Zhong, Christian Harcken, Hossein Razavi, Jonathan T. Reeves, Daniel R. Fandrick, Jinhua J. Song, Zhulin Tan, Soojin Kim, Bing-Shiou Yang, Nathan K. Yee, Chris H. Senanayake, Remy Angelaud, Daniel P. Sutherlin, Mark Reynolds, Scott Savage, Andreas Stumpf, Srinivasan Babu, Francis Gosselin, Theresa Humphries, Alan Olivero, Daniel Sutherlin, Qingping Tian, Erick W. Co, Julian P. Henschke
Publikováno v:
Journal of Organometallic Chemistry. 687:525-537
The reaction of iso-cinnamyl acetate with NaC(Me)(CO2Me)2, catalysed by Pd–‘MOP’ (MOP=2-methoxy-2′-diphenylphosphino-1,1′-binaphthalene) is known to proceed with a regiochemical memory effect that results in the predominant generation of th
Publikováno v:
Collection of Czechoslovak Chemical Communications. 68:907-916
The title compound 7 has been synthesized in a racemic form, using Suzuki coupling (8 + 15 → 16) as the key step. Pure enantiomer (S)-(-)-7 has been obtained by carbonylation of the known bromide (S)-(+)-12 followed by reduction of the resulting me
Autor:
Luděk Meca, Stephen C. Lockhart, Štěpán Vyskočil, Russel M. J. Stead, Iva Tišlerová, Yuri N. Belokon, Ivana Císařová, Pavel Kočovský, Louis J. Farrugia, William L. Mitchell, Miroslav Polášek, Syuzanna R. Harutyunyan
Publikováno v:
Chemistry, 8(20), 4633-4648. Wiley-VCH Verlag GmbH & Co. KGaA
The title binaphthyls 19 and 26, which are the positional isomers of 2-methoxy-2'-(diphenylphosphino)-1,1'-binaphthyl (MOP, 19) and 2-amino-2'-hydroxy-1,1'-binaphthyl (NOBIN, 26), have been synthesized by Suzuki coupling as the key step (10 + 15→18
Publikováno v:
Chemistry - A European Journal. 8:4443-4453
A quantitative two-term description of memory effects arising in Pd-catalysed allylic alkylation reactions formally proceeding through 'meso'-type pi-allylpalladium intermediates is presented. The utility of this description (stereochemical convergen
Publikováno v:
Collection of Czechoslovak Chemical Communications. 65:539-548
Reductive amination of 2-hydroxybenzaldehyde, using a combination of NaBH4 and (R)-[1,1'-binaphthalene]-2,2'-diamine, served as the key step in the synthesis of the potentially tetradentate ligands (R)-N,N'-bis(2-hydroxybenzyl)[1,1'-binaphthalene]-2,
Publikováno v:
Pure and Applied Chemistry. 71:1425-1433
The power of transition metal catalysis as a tool in organic synthesis is exemplified by the recent progress in the following areas: (i) diastereocontrol of Pd(0)-, Mo(0)-, and Ni(0)- catalyzed allylic substitution; (ii) Pd(0)-catalyzed asymmetric al
Publikováno v:
Tetrahedron Letters. 40:1993-1996
Tetrahydro analogues of [5]-, [6]- and [7]helicene have been easily prepared by intramolecular [2+2+2] cycloisomerization of appropriate triynes under CpCo(CO) 2 /PPh 3 or Ni(cod) 2 /PPh 3 catalysis. This nonphotochemical methodology allows enantiose
Publikováno v:
Tetrahedron Letters. 39:9289-9292
The title compound 3, synthesized in four steps from NOBIN (1), has been found to exhibit a dramatic accelerating effect on the Pd(0)-catalyzed Hartwig-Buchwald N-phenylation of amino alcohol 1 and diamine 8 with PhBr. Partial kinetic resolution was
Publikováno v:
Collection of Czechoslovak Chemical Communications. 63:515-519
Reductive alkylation of (R)-(+)-2,2'-diamino-1,1'-binaphthyl (1) with various ketones has been accomplished by means of NaBH4/H2SO4 in THF at room temperature. Bisalkylation predominated with the sterically less demanding acetone (1→3a; 82%), where