The Bioactivity of Xylene, Pyridine, and Pyrazole Aza Macrocycles against Three Representative Leishmania Species

Autor: Álvaro Martín-Montes, Álvaro Martínez-Camarena, Alberto Lopera, Irene Bonastre-Sabater, M. Paz Clares, Begoña Verdejo, Enrique García-España, Clotilde Marín

Publikováno v: Pharmaceutics, Vol 15, Iss 3, p 992 (2023)

Due to the urgent need for finding effective and free of secondary effect treatments for every clinical form of Leishmaniasis, a series of synthetic xylene, pyridine and, pyrazole azamacrocycles were tested against three Leishmania species. A total o

Externí odkaz: https://doaj.org/article/ad8ac51cb45b4c13b5eecf1d6dae6a86

Stabilisation of Exotic Tribromide (Br3−) Anions via Supramolecular Interaction with a Tosylated Macrocyclic Pyridinophane. A Serendipitous Case

Autor: Álvaro Martínez-Camarena, Matteo Savastano, Carla Bazzicalupi, Antonio Bianchi, Enrique García-España

Publikováno v: Molecules, Vol 25, Iss 14, p 3155 (2020)

Tetraaza-macrocyclic pyridinophane L-Ts, decorated with a p-toluenesulfonyl (tosyl; Ts) group, appear to be a useful tool to provide evidence on how the interplay of various supramolecular forces can help stabilise exotic anionic species such as trib

Externí odkaz: https://doaj.org/article/c204e2f101464628b0853e52089cef7b

Characterization of a Ferryl Flip in Electronically Tuned Nonheme Complexes. Consequences in Hydrogen Atom Transfer Reactivity

Autor: Valeria Dantignana, M. Carmen Pérez‐Segura, Pau Besalú‐Sala, Estefanía Delgado‐Pinar, Álvaro Martínez‐Camarena, Joan Serrano‐Plana, Andrea Álvarez‐Núñez, Carmen E. Castillo, Enrique García‐España, Josep M. Luis, Manuel G. Basallote, Miquel Costas, Anna Company

Publikováno v: Dantignana, Valeria Pérez-Segura, M. Carmen Besalú-Sala, Pau Delgado Pinar, Estefanía Martínez Camarena, Álvaro Serrano-Plana, Joan Álvarez-Núñez, Andrea Castillo, Carmen E. Garcia-España Monsonis, Enrique Luis, Josep M. Basallote, Manuel G. Costas, Miquel Company, Anna 2023 Characterization of a Ferryl Flip in Electronically Tuned Nonheme Complexes. Consequences in Hydrogen Atom Transfer Reactivity Angewandte Chemie 62 2 e202211361

Two oxoiron(IV) isomers (R2a and R2b) of general formula [FeIV(O)(RPyNMe3)(CH3CN)]2+ are obtained by reaction of their iron(II) precursor with NBu4IO4. The two isomers differ in the position of the oxo ligand, cis and trans to the pyridine donor. The

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::7064abc049c986d3b26810d8301575ef
https://doi.org/10.1002/ange.202211361

Inhibitory Effect of Azamacrocyclic Ligands on Polyphenol Oxidase in Model and Food Systems

Autor: Jose Vicente Ros Lis, Sara Muñoz-Pina, Álvaro Martínez-Camarena, Enrique García-España, Ángel Argüelles, Estefanía Delgado-Pinar, Ana María Andrés Grau, Begoña Verdejo

Publikováno v: RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
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[EN] Enzymatic browning is one of the main problems faced by the food industry due to the enzyme polyphenol oxidase (PPO) provoking an undesirable color change in the presence of oxygen. Here, we report the evaluation of 10 different azamacrocyclic c

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::524d7a128bc0ce98830d9aca6ae5e189
https://doi.org/10.1021/acs.jafc.0c02407

Stabilization of polyiodide networks with Cu(ii) complexes of small methylated polyazacyclophanes: shifting directional control from H-bonds to I⋯I interactions

Autor: Antonio Bianchi, Carla Bazzicalupi, Enrique García-España, Álvaro Martínez-Camarena, Matteo Savastano, José M. Llinares, Begoña Verdejo

Publikováno v: Inorganic Chemistry Frontiers. 7:4239-4255

Ordered polyiodide networks have recently gathered considerable attention as electronic materials, a topic historically dominated by metals. Could we incorporate metal cations into polyiodide frameworks in a controlled manner to simultaneously boost

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::5a84b103b919d035913d03fcfeaf6556
https://doi.org/10.1039/d0qi00912a