Competitive carbothiolation and sonogashira cross-coupling in the reaction of trimethylsilylacetylene with arylthioacetates

Autor: Valentina Iovine, [a] Federico Cruciani, [a] Flavio Picini, [a] Marta Varrone, [b] Enrico Rossi, [b] Mauro Bassetti, [b], Andrea D'Annibale*[a]

Publikováno v: ChemistrySelect 1 (2016): 5201–5205. doi:10.1002/slct.201601373
info:cnr-pdr/source/autori:Valentina Iovine,[a] Federico Cruciani,[a] Flavio Picini,[a] Marta Varrone,[b] Enrico Rossi,[b] Mauro Bassetti,*[b] and Andrea D'Annibale*[a]/titolo:Competitive carbothiolation and sonogashira cross-coupling in the reaction of trimethylsilylacetylene with arylthioacetates/doi:10.1002%2Fslct.201601373/rivista:ChemistrySelect/anno:2016/pagina_da:5201/pagina_a:5205/intervallo_pagine:5201–5205/volume:1

p-Bromo- or p-iodophenylthioacetate can react with trimethylsilylacetylene by simultaneous Sonogashira coupling at the halide function and addition of acetyl and arylthio moieties to the triple bond. Reaction of arylthioacetates with p-OMe, -Me, Ph a

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::522a36226057426581781b7d322ffe76
http://hdl.handle.net/11573/930138