Zobrazeno 51 - 60
of 70
pro vyhledávání: '"Patrick Rabe"'
Autor:
Christian A. Citron, Patrick Rabe, Michael Groll, Carina C. de Oliveira Mann, Jeroen S. Dickschat, Norman Kaufmann, Philipp Baer
Publikováno v:
ChemBioChem. 15:213-216
The biosynthesis of terpenes is catalysed by class I and II terpene cyclases. Here we present structural data from a class I hedycaryol synthase in complex with nerolidol, serving as a surrogate for the reaction intermediate nerolidyl diphosphate. Th
Publikováno v:
ChemInform. 47
A terpene cyclase from Streptomyces pristinaespiralis was characterized as the synthase for (+)-(2S,3S,9R)-pristinol. The structure of this sesquiterpene alcohol, which has a new carbon skeleton, was established by NMR spectroscopy and single-wavelen
Autor:
Jeroen S. Dickschat, Jonathan Gershenzon, Gad Shaulsky, Ayla Norris, Balaji Santhanam, Qidong Jia, Xinlu Chen, Feng Chen, Patrick Rabe, Tobias G. Köllner
Publikováno v:
ResearcherID
Proceedings of the National Academy of Sciences of the United States of America
Proceedings of the National Academy of Sciences of the United States of America
Terpenes are structurally diverse natural products involved in many ecological interactions. The pivotal enzymes for terpene biosynthesis, terpene synthases (TPSs), had been described only in plants and fungi in the eukaryotic domain. In this report,
Publikováno v:
Beilstein Journal of Organic Chemistry, Vol 9, Iss 1, Pp 2767-2777 (2013)
Beilstein Journal of Organic Chemistry
Beilstein Journal of Organic Chemistry
Two unidentified chlorinated volatiles X and Y were detected in headspace extracts of the fungus Geniculosporium. Their mass spectra pointed to the structures of a chlorodimethoxybenzene for X and a dichlorodimethoxybenzene for Y. The mass spectra of
Publikováno v:
ChemBioChem. 14:2345-2354
The volatile terpenes of 24 actinomycetes whose genomes have been sequenced (or are currently being sequenced) were collected by use of a closed-loop stripping apparatus and identified by GC/MS. The analytical data were compared against a phylogeneti
Publikováno v:
Angewandte Chemie (International ed. in English). 55(34)
A terpene cyclase from Streptomyces pristinaespiralis was characterized as the synthase for (+)-(2S,3S,9R)-pristinol. The structure of this sesquiterpene alcohol, which has a new carbon skeleton, was established by NMR spectroscopy and single-wavelen
Three sesquiterpene cyclases from Streptomyces scabei 87.22, Streptomyces venezuelae ATCC 10712 and Streptomyces clavuligerus ATCC 27064 were characterised and their products were identified as (-)-neomeranol B, (+)-isodauc-8-en-11-ol and (+)-interme
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::85cd93f577aa584bca8b0ef788d9ed6c
Publikováno v:
Angewandte Chemie, 55(43), 13593-13596. Wiley Online Library
Stereospecifically labelled precursors were subjected to conversion by seven bacterial sesquiterpene cyclases to investigate the stereochemistry of their initial 1,10-cyclisation-1,3-hydride shift cascades. Enzymes with products of known absolute con
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::a0390556988d4af673d4e721cee91b48
https://pure.knaw.nl/portal/en/publications/118cd1a3-9fb5-4129-8805-0acb4fce6980
https://pure.knaw.nl/portal/en/publications/118cd1a3-9fb5-4129-8805-0acb4fce6980
Publikováno v:
Angewandte Chemie. 124:4129-4133
Autor:
Patrick, Rabe, Lena, Barra, Jan, Rinkel, Ramona, Riclea, Christian A, Citron, Tim A, Klapschinski, Aron, Janusko, Jeroen S, Dickschat
An uncharacterized terpene cyclase from Streptomyces pratensis was identified as (+)-(1(10)E,4E,6S,7R)-germacradien-6-ol synthase. The enzyme product exists as two interconvertible conformers, resulting in complex NMR spectra. For the complete assign
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=pmid_dedup__::c59fa525222e510334ac08ad6340086f