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pro vyhledávání: '"Eri Nagashima"'
Autor:
Shinya Sato, Shogo Horie, Yuichi Murata, Yoshida Takuya, Yuta Yasuda, Eri Nagashima, Satoshi Matsunaga, Kenji Nomiya, Kohei Endo, Sho Shimazaki, Toshiaki Matsubara
Publikováno v:
Inorganic Chemistry. 57:1504-1516
Novel intercluster compounds consisting of pentakis[(triphenylphosphane)gold]ammonium(2+) cation (1) and Keggin polyoxometalate (POM) anions, i.e., {[Au(PPh3)]5(μ5-N)}3[α-PM12O40]2 (1-PW for M = W; 1-PMo for M = Mo), were synthesized in 30–36% yi
Publikováno v:
Dalton Transactions. 45:13565-13575
The effect of counteranions on the molecular structures of phosphanegold(i) cluster cations formed by polyoxometalate (POM)-mediated clusterization was investigated. A novel intercluster compound, [{(AuLCl)2(μ-OH)}2]3[α-PMo12O40]2·3EtOH (1-PMo12),