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pro vyhledávání: '"Ryan P. King"'
Publikováno v:
Org Lett
Palladium oxidative addition complexes (OACs) have recently emerged as useful tools to enable challenging bond connections. However, each OAC can only be formed with one dative ligand at a time. As no one ligand is optimal for every cross- coupling r
Autor:
Ryan P. King, Stephen L. Buchwald
Publikováno v:
Organometallics. 38:3490-3493
In palladium-catalyzed aryl–trifluoromethyl cross-coupling reactions, reductive elimination is often the rate-limiting step. Stoichiometric studies of reductive elimination have proved effective in evaluating the ability of various ligands to facil
Publikováno v:
Org Lett
The utilization of isolated Palladium Oxidative Addition Complexes (OACs) has had a significant impact on Pd-catalyzed and Pd-mediated cross-coupling reactions. Despite their importance, widespread utility of OACs has been limited by the instability
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::80a7fe8b89457acfe99a27cbb6eab1a3
https://europepmc.org/articles/PMC9235910/
https://europepmc.org/articles/PMC9235910/
Publikováno v:
Science. 363:405-408
Embedding palladium ahead of time Palladium-catalyzed cross-coupling is one of the most widely applied reaction classes in pharmaceutical research. The metal is adept at connecting aromatic rings to one another or to nitrogen centers. However, functi