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pro vyhledávání: '"James E. House"'
Autor:
James E. House, Rebekah M. Nulty
Publikováno v:
Polyhedron. 134:173-176
The solubility of ferrocene in commercial mixed solvents containing 50, 70, and 91% 2-propanol and water has been determined as a function of temperature. From the solubility data, the values of ΔH, ΔS, and ΔG for the dissolution process have been
Autor:
James E. House, Kathleen A. House
Publikováno v:
Journal of Molecular Liquids. 242:428-432
A study has been carried out by making use of published data for the solubility of urea to evaluate the thermodynamic quantities associated with the dissolution of urea in water, alcohols, and mixture of these solvents. The Δ G values show an increa
Publikováno v:
Polyhedron. 53:240-242
The solubility of ferrocene in n-octane, methanol, and acetonitrile has been determined as a function of temperature in the range 0–30 °C using a spectrophotometric technique. From the variation in solubility with temperature, the enthalpies of so
Autor:
James E. House, Debbie Beck Hamilton
Publikováno v:
Transition Metal Chemistry. 19:527-530
The deaquation-anation of solid aquapentamminecobalt(III) chloride was studied isothermally and non-isothermally. Kinetic data were obtained from t.g.a. and were analysed using 17 rate laws known for solid state reactions. This reaction, long interpr
Autor:
Nicholas E. Kob, James E. House
Publikováno v:
Transition Metal Chemistry. 19:31-33
Heating Ag3[Co(CN)6]·16H2O results in dehydration and complete conversion of the Ag+ NC -Co3+ linkages to Ag+ -CN -Co3+. These processes have been studied kinetically. The dehydration process follows an R1, one dimensional contraction, rate law and
Autor:
L. A. Marquardt, James E. House
Publikováno v:
Transition Metal Chemistry. 18:548-550
The decomposition of piperidinium hexathiocyanatochromate(III), (pipH)3[Cr(NCS)6](s), into Cr(NCS)3(s) and pipHSCN(g) has been studied isothermally and nonisothermally using t.g.a. Data from isothermal studies were analysed according to 17 different
Autor:
Randal W. Eveland, James E. House
Publikováno v:
Transition Metal Chemistry. 19
The dehydration of trans-[Co(NH3)4Cl2)IO3·2H2O was studied isothermally by t.g.a. In the 0.1 < α < 0.8 range, where α is the fraction of the reaction complete, most of the runs gave the best fit to a second order rate law. Early stages of the reac