Zobrazeno 1 - 10
of 82
pro vyhledávání: '"Norrish, A."'
Publikováno v:
Progress in Reaction Kinetics and Mechanism. 27:49-72
The method of flash photolysis has been used to initiate the reaction between hydrogen and oxygen, using a small amount of nitrogen dioxide as sensitizer. The dependence of the ignition limits on total pressure, capacity and the pressure of nitrogen
Publikováno v:
Proceedings of the Royal Society of Medicine. 187(1010 Ser)
The controversy which exists at the present time between the figures 125 and 170 kcal./g.- atom for the latent heat of sublimation of carbon into monatomic vapour in the ground state originates largely from the neglect to take into consideration the
Publikováno v:
Proceedings of the Royal Society of London. A. Mathematical and Physical Sciences. 344:1-19
Polyvinyl bromide in solution, in dry tetrahydrofuran (THF) yields a black polymer upon exposure to u.v. light of 260 nm or less. This is shown to be the result of (a) the elimination of bromine atoms in the primary reaction, and (b) the catalysed fo
Publikováno v:
Proceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences. 301:1-37
It is appropriate for us to contemplate the growth of understanding of chemical kinetics which has taken place since the time of Planck. Understanding starts with the recognition by Stark in 1908 of the photon as an elementary particle in chemical re
Publikováno v:
Proceedings of the Royal Society of London. Series A - Mathematical and Physical Sciences. 150:36-57
A comprehensive theory of the combustion of hydrocarbons must describe in detail all the analytic and kinetic data. Up to the present no such theory has been proposed, for though the hydroxylation theory of Bone and his school has been very successfu
Publikováno v:
Proceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences. 227:423-433
The absorption spectra of explosions of ethylene, ethane and methane with oxygen, initiated by the flash photolysis of nitrogen dioxide, have been studied kinetically by flash spectroscopy and the results are compared with those already given for ace
Publikováno v:
Proceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences. 254:147-162
The identity and behaviour of free radicals produced during the combustion of gaseous aldehydes has been examined. The flash-initiated combustion of formaldehyde was investigated under conditions of slow and explosive combustion. The behaviour of for
Mechanism of the formation of halogen monoxides during flash photolysis of halogen + oxygen mixtures
Publikováno v:
Proceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences. 271:289-295
The mechanism of the formation of BrO and CIO in the flash photolysis of halogen + oxygen mixtures was investigated. It was found that the predominant mechanism for the production of BrO (about 90 % in our experiments) involves the absorption of ligh
Publikováno v:
Proceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences. 275:310-337
The kinetics of the Ziegler-catalyzed polymerization of ethylene have been studied in a static system in the complete absence of any hydrocarbon vehicle. The apparatus which was developed consisted essentially of two mixing vessels, each of which was
Publikováno v:
Proceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences. 308:305-325
The gas phase oxidation of neopentane has been studied in a static system at 280 °C. It is shown that the main course of the reaction is best understood as a degenerately branched chain reaction propagated by the hydroxyl radical. Two simultaneous r