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Publikováno v:
Topics in Catalysis. 65:383-391
Intermolecular radical coupling (also interaction of two metal centers I2M) is one of the main mechanisms for O–O bond formation in water oxidation catalysts. For Ru(bda)L2 (H2bda = 2,2′-bipyridine-6,6′-dicarboxylate, L = pyridine or similar ni
Publikováno v:
Bulletin of the Chemical Society of Japan. 94:2048-2053
For post-transition metal electrocatalytic hydrogen evolution reaction (HER), the new porphycene antimony complexes, Sb(III)OEPo and Sb(V)OEPo-Br2, were synthesized and characterized. Based on the ...
Autor:
Konstantinos A. Lazarou, Kevin Fabrizio, Carl K. Brozek, Stephen L. Golledge, Liam P. Twight, Lillian I. Payne, Christopher H. Hendon
Publikováno v:
Journal of the American Chemical Society. 143:12609-12621
Titanium-based metal-organic frameworks (Ti-MOFs) have attracted intense research attention because they can store charges in the form of Ti3+ and they serve as photosensitizers to cocatalysts through heterogeneous photoredox reactions at the MOF-liq
Autor:
Chenxin Yang, Sheng Xie, Wangwang Peng, Huiping Xiao, Bo Li, Xinhao Wang, Jishan Wu, Shenglian Luo, Guangwu Li, Zebing Zeng
Publikováno v:
Angewandte Chemie International Edition. 60:19790-19796
We report an anti-folded bowl-shaped bisdibenzocorannulene (BDBC) featuring a new chair-cyclohexane-like hexagon as a bridge of two dibenzocorannulene moieties. The neutral compound showed multiple redox-active properties and could be converted to th
Autor:
Hyungjun Kim, Tae Joo Shin, June Sung Lim, Jinjong Kim, Sang Hoon Joo, Kug-Seung Lee, Jae Hyung Kim, Vinod K. Paidi, Hu Young Jeong, Dongyup Shin
Publikováno v:
Angewandte Chemie. 133:20691-20697
Rational control of the coordination environment of atomically dispersed catalysts is pivotal to achieve desirable catalytic reactivity. We report the reversible control of coordination structure in atomically dispersed electrocatalysts via ligand ex
Autor:
Hannu Häkkinen, María Francisca Matus, Run Shi, Qiaofeng Yao, Sami Malola, Tiankai Chen, Yitao Cao, Jianping Xie
Publikováno v:
Chem. 7:2227-2244
Most inorganic nanoparticles are directly surface-terminated (and -stabilized) by protecting ligands, which could greatly affect the atomic packing and physical/chemical properties of their inorganic cores. Here, we show that the intermolecular inter
Autor:
Eva Martínez-Ahumada, Ashley M. Wright, Pengbo Lyu, Daryl R. Williams, Alfredo López-Olvera, Mircea Dincă, Paulo G. M. Mileo, Guillaume Maurin, J. Antonio Zárate, Ilich A. Ibarra, Vladimir Martis
Publikováno v:
Chemistry of Materials
Chemistry of Materials, American Chemical Society, 2021, 33 (15), pp.6186-6192. ⟨10.1021/acs.chemmater.1c01838⟩
Chemistry of Materials, American Chemical Society, 2021, 33 (15), pp.6186-6192. ⟨10.1021/acs.chemmater.1c01838⟩
International audience
Autor:
Robert M. Christie, Adrian Abel
Publikováno v:
Physical Sciences Reviews. 6:569-580
Perylenes and perinones are separate groups of pigments categorized within the carbonyl chemical class. The two pigment groups show similarities, for example, in their chemical structural features and, to an extent, in their technical and application
Autor:
Wei Liu, Haoran Lin, Yumeng Shi, Biwu Ma, Hanlin Hu, Kang Zhou, Shaofan Fang, Fang Lin, Guicheng Yu
Publikováno v:
Chemistry of Materials. 33:5668-5674
Autor:
Tetsuro Kusamoto, Shun Kimura
Publikováno v:
Chemistry Letters. 50:1445-1459
Stable organic radicals with unpaired electrons exhibit vivid physical characteristics such as magnetic and electron-conducting properties, while being assumed as non-emissive chemical species. Thi...