Zobrazeno 1 - 10
of 16
pro vyhledávání: '"Kunio Mochida"'
Publikováno v:
European Journal of Inorganic Chemistry. 2012:4791-4794
Reactions of zero-valent platinum complexes having a diphosphane ligand with arylgermanes ArGeH3 [Ar = 2,4,6-trimethylphenyl (Mes); 2,4,6-triethylphenyl (TEP)] in a 1:2 molar ratio yield several bis(germyl)platinum complexes. The complex containing a
Publikováno v:
Organometallics. 30:917-920
Treatment of [Pt(L2)(η2-C2H4)] (L2 = dppe or (PPh3)2) with H3SiSiMe2tBu at room temperature afforded the corresponding trigonal bipyramidal clusters [Pt3(L2)3(μ3-SiH)2]. In the case of L2 = dppe, the octahedral cluster [Pt4(dppe)4(μ4-SiH)2] and th
Publikováno v:
European Journal of Inorganic Chemistry. 2004:2961-2967
Tris(trimethylsilyl)-substituted group 14-element-centered anion monomers [LiE(SiMe3)3·3THF] (E = Si, Ge, and Sn) can be distilled under reduced pressure to give dimeric silyllithium 4 and stannyllithium 6, and trimeric germyllithium 5 without pyrol
Autor:
Masahiro Kako, Kunio Mochida, Masanori Yasui, Seiji Kakuma, Yasuhiro Nakadaira, Matsumoto Fuyuhiko, Fujiko Iwasaki, Masakatsu Shimoda, Haruhiko Komoriya, Masao Yashikawa
Publikováno v:
Bulletin of the Chemical Society of Japan. 73:1403-1408
By X-ray crystallographic analysis, the molecular structure of 3,4,7,8-tetragermacycloocta-1,5-diyne 1b has been established to be planar and quite similar to that of silicon analog 3,4,7,8-tetrasilacycloocta-1,5-diyne 1a. The detailed comparison of
Publikováno v:
Inorganic Chemistry Communications. 9:50-52
Self-assembly reactions of di{4-(5-pyrimidyl)phenyl}dimethylsilane and -germane with (ethylenediamine)palladium dinitrate in ratio of 1:2 led to the formation of new octahedral supramolecules containing group 14 elements (Si,Ge), respectively. The st
Publikováno v:
Organometallics. 24:4337-4339
The reaction of Pt(η2-C2H4)(PPh3)2 (1) with HPh2Ge(SiMe2)nGePh2H (2; n = 0−3) initially forms the hydrido(germyl)platinum complex cis-Pt(H)[GePh2(SiMe2)nGePh2H](PPh3)2 (3), followed by the generation of the cyclic bis(germyl)platinum complex (4) a
Publikováno v:
NIPPON KAGAKU KAISHI. :202-207
Publikováno v:
ChemInform. 39
Dibenzodehydro[16]annulenes containing silicon–silicon and germanium–germanium σ bonds were newly prepared, and their structures were established by spectroscopic methods and X-ray diffraction anal...
Publikováno v:
Bulletin of the Chemical Society of Japan. 66:2773-2775
The crystal and molecular structures of octaisopropylcyclotetragermane, [(i-Pr)2Ge]4 have been determined by X-ray diffraction at room temperature. The triclinic structure was refined by the full matrix least-squares method to a final R = 0.049 for 5
Publikováno v:
Chemistry Letters. 37:20-21
Dibenzodehydro[16]annulenes containing silicon–silicon and germanium–germanium σ bonds were newly prepared, and their structures were established by spectroscopic methods and X-ray diffraction anal...