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Autor:
Shuvankar Naskar, Jens Müller
Publikováno v:
Inorganic Chemistry. 60:14765-14771
Metal-mediated base pairs enable a site-specific incorporation of transition metal ions into nucleic acid structures. The resulting nucleic acid-metal complex conjugates are of interest in the context of functionalized nucleic acids, as they bear met
Publikováno v:
Nucleosides, Nucleotides & Nucleic Acids. 40:845-866
A novel Schiff base ligand, 4-fluoro-N-((3-hydroxy-5-(hydroxymethyl)-2-methylpyridin-4-yl)methylene)benzohydrazide (PLFBH) was synthesized by condensationof pyridoxal and 4-fluorobenzohydrazide. Its complexes with Ni(II), Cu(II), and Zn(II) metal ion
Autor:
Kathleen E. Prosser, Gregory A. MacNeil, Rahul T. Kadakia, Annica Chu, Da Xie, Emily L. Que, Bryton R. Varju, Charles J. Walsby
Publikováno v:
Chemistry – A European Journal. 27:9839-9849
Targeting the low-oxygen (hypoxic) environments found in many tumours by using redox-active metal complexes is a strategy that can enhance efficacy and reduce the side effects of chemotherapies. We have developed a series of CuII complexes with tride
Autor:
Julian Heinrich, Phil Liebing, Carsten Lüdtke, Sebastian Sobottka, Biprajit Sarkar, Nora Kulak, Stefanie Wedepohl
Publikováno v:
Chemistry – A European Journal. 27:3273-3277
[Cu(phen)2 ]2+ (phen=1,10-phenanthroline) is the first and still one of the most efficient artificial nucleases. In general, when the phen ligand is modified, the nucleolytic activity of its CuII complex is significantly reduced. This is most likely
Publikováno v:
Journal of Fluorescence. 30:471-482
Pyrimidine derivative Schiff base ligand (DPMC) stabilized metal nanoparticles of copper (DPMC-CuNPs) and nickel (DPMC-NiNPs) were synthesized by modified Brust-Schiffrin technique, which is a two-step phase transfer assisted synthesis. The prepared
Publikováno v:
Nucleosides, Nucleotides & Nucleic Acids. 39:630-647
Contemporary research reveals an undemanding protocol for the catalytic synthesis of 1,2,4-oxadiazole-quinolinepeptide in the incidence of a cost-effective and reusable mesoporous ZrO2-supported Cu2O (Cu2ZrO3) catalyst. This paper depicts a unique sy
Autor:
Ribhu Maity, Saptarshi Mukherjee, Tithi Maity, Nayim Sepay, Kalyanmoy Jana, Swapan Maity, Bidhan Chandra Samanta, Dasarath Mal, Ushasi Pramanik
Publikováno v:
The journal of physical chemistry. B. 125(41)
In the present study, a dinuclear bis(μ-acetate) dicopper(II) complex [Cu2L2(μ1.1-CH3COO-)2] has been synthesized from a tridentate NNO Schiff Base ligand L (L = 2,4-dibromo-6-((3-(methylamino)propylimino)methyl)phenol) and characterized by element
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Autor:
Poonam R. Inamdar, Angappan Sheela
Publikováno v:
Nucleosides, nucleotidesnucleic acids. 40(5)
Multidentate copper metal complexes have been in the limelight in the area of DNA interaction studies exhibiting intercalation, groove binding and cross linking modes. Design of metal complex based on the versatile ligands decides their mode of DNA b
Autor:
Anandaram Sreekanth, K.N. Aneesrahman, Nattamai Bhuvanesh, G.P. Stefy, K. Ramaiah, Gandhaveeti Rohini
Publikováno v:
Inorganica Chimica Acta. 492:131-141
The newly synthesized ligands (HL1-HL3) of 5-methoxyisatin thiosemicarbazone with different N-terminal substituents and their copper(II) complexes 1–3 respectively were exposed to spectral and structural characterization. The spectral studies revea