Zobrazeno 1 - 10
of 36
pro vyhledávání: '"Alan L. Balch"'
Publikováno v:
Chemistry – A European Journal. 25:2491-2496
Carbon disulfide is cleaved by n-propyldiphenylphosphine and nickel(II) bromide in a one-step process, to form two unprecedented complexes: orange, [Ni(S2 C2 (Pn PrPh2 )2 )Br(Pn PrPh2 )]Br⋅CS2 (1) and purple [Ni{η2 -SC(Pn PrPh2 )2 }Br(Pn PrPh2 )]B
Autor:
Alan L. Balch, Ahmad R. Esmaeilbeig, Kamran B. Ghiassi, Fatemeh Raoof, S. Masoud Nabavizadeh, Maryam Boostanizadeh, Marilyn M. Olmstead, Reza Babadi Aghakhanpour
Publikováno v:
RSC Advances. 5:85111-85121
The compound [PtMe(bzpy)(DMSO)] (1; bzpy = 2-benzylpyridinate) was synthesized by reaction of cis-[PtMe2(DMSO)2] with 1 equiv. of bzpyH under reflux conditions in toluene through C–H activation of the carbon–hydrogen bond in 2-benzylpyridine. The
Publikováno v:
Inorganic Chemistry. 40:1454-1458
Binuclear [FeIIFeIII(BMDP)(O2CPh)3](BF4) (1) was obtained by treating an acetonitrile solution of the fully reduced [FeIIFeII(BMDP)(O2CPh)(MeOH)1.5(H2O)0.5](BF4)2 with 5 equiv of benzoate and then exposing the mixture to oxygen. Examination of [FeIIF
Publikováno v:
Journal of the American Chemical Society. 122:12478-12486
Treatment of iron(II) porphyrins, (py)2FeII(OEP), (py)2FeII(EtioP), (py)2FeII(DeuteroP), (py)2FeII(MesoP), and (py)2FeII(ProtoP), where OEP are the dianions of octaethylporphyrin, etio-1 porphyrin, deuteroporphyrin-IX dimethyl ester, mesoporphyrin-IX
Publikováno v:
Chemistry - A European Journal. 3:268-278
The nickel(I) and nickel(II) complexes of 5,20-bis(p-tolyl)-10, 15-diphenyl-21-oxaporphyrin (ODTDPPH) and 5,10,15,20-tetraphenyl-21, 23-dioxaporphyrin (O2 TPP) have been investigated. These oxa analogues of 5,10,15,20-tetraarylporphyrin, where one or
Publikováno v:
Journal of the American Chemical Society. 115:9056-9061
The coupled oxidation process, which is a model for oxidative heme degradation, has been shown to produce not only verdoheme, which was first described in 1930, but also a paramagnetic iron complex. Treatment of (0EP)- FeI1(py)2 (OEP is the dianion o
Publikováno v:
Inorganic Chemistry. 32:3613-3619
Investigation of the reaction between (t-BuNC) 2 PdCl 2 and mer-Mo(dpm-P,P')(dpm-P)(CO) 3 (dpm=bis-(diphenylphospbino)methane) has produced two complexes that combine a d 6 and a d 8 metal center. The reaction in dichloromethane yields green [(t-BuNC
Publikováno v:
Inorganica Chimica Acta. 187:181-186
Treatment of mercury(II) chloride with dpmp (dpmp is bis(diphenylphosphinomethyl)phenylphosphine) yields a mixture of HgCl 2 (dpmp) and [Hg 3 (μ-Cl) 2 (μ-dpmp) 2 ]Cl 2 .With mercury(II) bromide and iodide, only HgXe(dpmp) forms. [Hg 3 (μ-Cl 2 )Cl
Tetrapyrroles as π Donors: A Pd22+ Unit Sandwiched between Two Helical Bilindione-Palladium Moieties
Publikováno v:
Angewandte Chemie International Edition. 38:2761-2763
Metalation of octaethylbilindione (H(3)OEB) with palladium(II) acetate produces the novel tetranuclear complex [Pd(4)(OEB)(2)] in which a (Pd(I)(2))(2+) unit is sandwiched between two helical Pd(OEB) units (see picture). Treatment of [Pd(4)(OEB)(2)]
Publikováno v:
Inorganic Chemistry. 29:1638-1642
Addition of tetrachloro-1,2-benzoquinone to bi- and trinuclear rhodium complexes results in conversion of terminal carbon monoxide ligands to bridging ones and the formation of new Rh-Rh bonds. Reaction of tetrachloro-1,2-benzoquinone with Rh 2 (CO)