Zobrazeno 1 - 10
of 17
pro vyhledávání: '"Bernhard Metz"'
Autor:
Bernhard Metz, Frank H. Köhler, Basil Kanellakopulos, Rodrigue Lescouëzec, Christoph Elschenbroich, Norbert W. Mitzel, Werner Strauß
Publikováno v:
Chemistry - A European Journal. 13:1191-1200
The reaction of [{(C5Me5)-CrCl2}(2)] with [2.2](1,4)cyclophane gave [(C5Me5)Cr{[2.2](1,4)cyclophane}] (1) and [(C5Me5)Cr{[2.2](1,4)cyclophane}-Cr(C5Me5)] (2), depending on the reaction conditions. X-ray structure analysis showed 2 to be a ministack w
Autor:
Bernhard Metz, William E. Geiger, Neil G. Connelly, Rainer F. Winter, Timothy J. Paget, Sherri R. Lovelace
Publikováno v:
Organometallics. 18:3201-3207
The complexes [M(NCMe)(RC2R)2(η-C5R‘5)]+ (M = Mo or W, R = Me or Ph; R‘ = H or Me, C5R‘5 = C5HPh4) undergo one-electron reduction to [M(NCMe)(RC2R)2(η-C5R‘5)], which rapidly lose acetonitrile to give the 17-electron complexes [M(RC2R)2(η-C
Autor:
Klaus Harms, Reinhart Möckel, Christoph Elschenbroich, Alexander Yu. Vasil’kov, Bernhard Metz
Publikováno v:
European Journal of Inorganic Chemistry. 1998:1391-1401
The sandwich complexes bis(η6-triphenylene)chromium (12) and bis(η6-fluoranthene)chromium (13) have been prepared by means of metal atom/ligand vapor cocondensation. Whereas for triphenylene exclusive coordination to the peripheral rings is observe
Autor:
Bernhard Metz, Eckhardt Schmidt, Rolf Gondrum, Olaf Burghaus, Christoph Elschenbroich, Sigrid Wocadlo, Werner Massa
Publikováno v:
Organometallics. 16:4589-4596
Mono- and digerma[n]metallocyclophanes (n = 1, 2) [(η6,η6‘-dimethyldiphenylgermane)M] (M = Cr, 17; V, 18•), [(η6,η6‘-tetraphenylgermane)M] (M = Cr, 20; V, 21•), and [(1,1,2,2-tetramethyl-1,2-di-η6,η6‘-phenyldigermane)Cr] (24) were syn
Publikováno v:
Journal of Cluster Science. 6:125-134
Treatment of [W(CO)(MeC2Me)2(η-C5H5)][PF6] with ONMe3 in acetonitrile yields [W(NCMe)(MeC2Me)2(η-C5H5)][PF6] which undergoes irreversible reduction at a Pt electrode in THF. Sodium amalgam reduction of [W(NCMe) (MeC2Me)2(η-C5H5)][PF6] gives orange
Publikováno v:
Journal of Organometallic Chemistry. 481:153-165
Taking advantage of the ability of R2P-substituted derivatives of bis(benzene)chromium and bis(benzene)vanadium to act as organometallic ligands, we have prepared the di- and tri-nuclear complexes [(η)6-C6H6)(Me2P-η6-C6H5)Cr](η5-MeC5H4)(CO)2Mn) (3
Autor:
Christoph Elschenbroich, Friedrich Baer, Bernhard Metz, Dagmar Mahrwald, Edgar. Bilger, Mathias Nowotny
Publikováno v:
Organometallics. 12:3373-3378
Autor:
Edward Reijerse, Esther K. Den Van Beuken, P. J. A. Maurice Hermans, Alex B. Scholten, Bernhard Metz, Jan M. M. Smits, Jürgen Heck, Annie Roeloffsen, Paul T. Beurskens, W. P. Bosman, Hugo C. Bussaard
Publikováno v:
Chemische Berichte. 126:553-563
Cooperative Effects in π1-Ligand-Bridged Dinuclear Complexes, XIII[1]. – Unexpected Weak d-d Interactions in Synfacial Heterodinuclear μ1-Cyclooctatetraene Complexes of the Type {(CpCr)[(CO)3M′]}μ1-Cot (M′Fe, Cr, W) The heterodinuclear compl
Publikováno v:
Chemische Berichte. 126:399-404
Metal π Complexes of Benzene Derivatives, XLI[1]. — Bis(η61-aniline)chromium: Synthesis, Redox Properties and Bronsted Basicity Bis(η61-aniline)chromium (6) has been prepared by protodesilylation of its N,N,N′,N′1-tetrakis(trimethylsilyl) de
Publikováno v:
ChemInform. 23