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Autor:
Xingyi Lin, Lilong Jiang, Hongfang Cai, Ying Zheng, Yanliang Zhou, Tianhua Zhang, Cong-Qiao Xu, Lingling Li, Bingyu Lin, Ya-Fei Jiang, Jun Li, Chak-Tong Au, Lirong Zheng, Xiuyun Wang
Publikováno v:
Chem. 8:749-768
Summary Ammonia synthesis is structure sensitive, and a minute change in the catalyst structure would cause a dramatic change in activity. To date, none of the studies reveal the metal size effect at a subnanometer scale on NH3 synthesis, and such in
Autor:
Marina Freitag, Michael R. Probert, Ana B. Muñoz-García, Michele Pavone, Iacopo Benesperi, Tomas Edvinsson, Hannes Michaels, Paul G. Waddell
Publikováno v:
Chem. 8:439-449
Summary Conventional redox mediators based on metal coordination complexes undergo electron transfer through the change in oxidation state of the metal center. However, electron transfer kinetics are offset toward preferred oxidation states when preo
Publikováno v:
Polymer Bulletin.
In order to improve the thermal conductivity of epoxy resins (EP) without reducing their dielectric properties, a kind of molybdenum disulfide with microspheres structure (S-MoS2) was prepared via surfactant promoting hydrothermal process based on th
Publikováno v:
Chemical Papers. 76:2279-2291
Mycosporine-like amino acids (MAAs) are low molecular-weight (
Publikováno v:
New Journal of Chemistry. 46:15-38
Due to widespread applications of sulfur-containing frameworks, the construction of the C-S bond has emerged as a useful tool for synthetic organic and medicinal chemists in recent years. Initially, the C-S bond formations were carried out under tran
Publikováno v:
Chemical Communications. 58:64-67
We report herein the first example of the controlled isomerisation of a C,Cʹ-bound (to metal) bis(ortho-carborane) ligand to C,Bʹ-bound with no other change in the molecule. Since the C and B vertices of carboranes have different electron-donating
Autor:
Pinky Satija, Pawan, María Ángeles Esteban, Priyanka, Gurjaspreet Singh, Sushma, Jashandeep Kaur, Cristóbal Espinosa-Ruíz, Kashmir Singh
Publikováno v:
New Journal of Chemistry. 46:370-384
This article highlights the design and synthesis of Schiff base of veratraldehyde based organosilatranes and organosilocanes (3a-3c) and these were meticulously characterized with the aid of NMR (1H and 13C) and mass spectroscopic techniques. Moreove
Publikováno v:
Journal of Materials Chemistry C. 10:2592-2599
Conjugated coordination polymers (CCPs) have attracted extensive attention for energy storage in the past few years. However, the rational design and controllable synthesis of CCPs remain challenging, which prevents gaining insight into the relations
Autor:
Wei Gu, Xiangyi Liu, Lei Wang, Liang Qin, Dongxu Jiang, Jinchao Feng, Liya Hong, Haiqiang Liu, Hao Hu, Kun Xue, Yijun Zhou, Xiaodong Wang, Yiyang Shi, Ran Wu, Qichen Hao
Publikováno v:
Chemical Communications. 58:633-636
Michler's ethylketone (MEK, 4,4’-bis(diethylamino)benzophenone), commonly-known as an intermediate in the synthesis of dyes and pigments, was successfully screened and optimized as a novel matrix for the enhancement of lipid in situ detection and i
Autor:
Mercedes M. A. Mazza, Dario Pasini, Daniele Dondi, Sara Benedini, Andrea Nitti, Yeting Zheng, Françisco M. Raymo
Publikováno v:
New Journal of Chemistry. 46:221-227
We report on two different series of conjugated push-pull compounds bearing dimethylamino donor and 1,3-dicarbonyl acceptor functionalities with a “bent” or“cruciform” shape, exhibit striking differences in their supramolecular recognition of