Zobrazeno 1 - 7
of 7
pro vyhledávání: '"Attila Sisak"'
Publikováno v:
Inorganica Chimica Acta. 227:297-300
The rate of acetylcobalt tetracarbonyl methanolysis between 40 and 60 °C is first-order with respect to the acetylcobalt tetracarbonyl concentration and independent of the carbon monoxide concentration. The reaction is susceptible to both acid and b
Publikováno v:
Inorganica Chimica Acta. 222:131-134
The hydrosilylation of carbon monoxide with cobalt carbonyls under relatively mild conditions resulted in a Fischer-Tropsch-analogous reductive coupling of CO. Alkyl silyl ethers, 1,2-bis(silyloxy)-1-alkenes and higher molecular weight compounds with
Publikováno v:
Journal of Organometallic Chemistry. 451:53-57
It has been shown that (β-silyloxyacyl)cobalt tetracarbonyls are formed in the reaction between silylcobalt tetracarbonyl, terminal oxirane, and carbon monoxide. The linear acyl isomer is obtained with a regioselectivity of about 80%, which is pract
Publikováno v:
Journal of Molecular Catalysis. 75:L27-L31
Publikováno v:
Journal of Organometallic Chemistry. 417:89-97
The rate of CO uptake in the reaction of HCo(CO) 4 with ethyloxirane, which gives (3-hydroxypentanoyl)cobalt tetracarbonyl as the major product in an n-octane/methyl isobutyl ketone solvent mixture at 15° C, is first order with respect to HCo(CO) 4
Publikováno v:
Journal of Organometallic Chemistry. 90:77-83
In reactions of Co 4 (CO) 9 (arene) with carbon monoxide, phosphines and acetylenes, displacement of the arene takes place and known derivatives of Co 4 (CO) 12 and Co 2 (CO) 8 are formed. With phosphites, however, displacement of one carbon monoxide
Autor:
Attila Sisak, László Markó
Publikováno v:
Journal of Organometallic Chemistry. 330:201-206
The disproportionation of Co2(CO)8 and pyridine are fractional, and depend on the partial CO pressure. A radical mechanism with partial chain character is proposed. The reaction appears to involved inner sphere electron transfer processes.