Zobrazeno 1 - 10
of 13
pro vyhledávání: '"Iapalucci, Maria Carmela"'
Publikováno v:
Accounts of Chemical Research. 51:2748-2755
Chemical research in synthesizing metal nanoparticles has been a major topic in the last two decades, as nanoparticles can be of great interest in many fields such as biology, catalysis, and nanotechnology. However, as their chemical and physical pro
Publikováno v:
ACS Omega, Vol 3, Iss 10, Pp 13239-13250 (2018)
This article describes a rare case of cluster core isomerism in a large molecular organometallic nanocluster. In particular, two isomers of the [HCo15Pd9C3(CO)38]2- nanocluster, referred as TP-Pd9 and Oh-Pd9, have been structurally characterized by s
Autor:
Rita Mazzoni, Iacopo Ciabatti, Cristiana Cesari, Cristina Femoni, Mohammad Hayatifar, Marco Bortoluzzi, Maria Carmela Iapalucci, Stefano Zacchini
Publikováno v:
Journal of Cluster Science. 28:703-723
The reaction of the Collman’s reagent Na2Fe(CO)4 with two equivalents of Au(NHC)Cl (NHC = IMes, IPr, IBu) in thf results in the bimetallic Fe(CO)4(AuNHC)2 (NHC = IMes, 2; IPr, 3; IBu, 4; IMes = C3N2H2(C6H2Me3)2; IPr = C3N2H2(C6H 3 i Pr2)2; IBu = C3
Autor:
Giuliano Longoni, Iacopo Ciabatti, Stefano Zacchini, Alessandro Bernardi, Maria Carmela Iapalucci, Cristina Femoni
Publikováno v:
Journal of Organometallic Chemistry. 812:229-239
The reaction of [Ni 10 (C 2 ) (CO) 16 ] 2– with CuCl in thf affords [Ni 45 C 10 (CO) 46 ] 6– as the major product. This represents the first deca-carbide carbonyl cluster and this is the highest number of C-atoms found in a molecular cluster. Bes
Autor:
Stefano Zacchini, Stefano Stagni, Mohammad Hayatifar, Iacopo Ciabatti, Irene Maggiore, Cristina Femoni, Maria Carmela Iapalucci
Publikováno v:
Journal of Cluster Science. 27:431-456
The reaction of [Fe4C(CO)(12){Cu(MeCN)}(2)] (1) with 3 equivalents of L-L (phen or Me(2)phen) affords [Cu(L-L)(2)][Fe4C(CO)(12){Cu(L-L)}] (L-L = phen, 2; Me(2)phen, 3) in good yields. These are protonated by strong acids resulting in [HFe4C(CO)(12){C
In this review, the authors describe the role of gold in the chemistry of transition metal carbonyl clusters, a field that has been very active over the past fifty years. Both homo- and heteroleptic Au-containing species of metal carbonyl clusters, f
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::2652377ba8aa8f903eb260f9a2ed17c1
https://hdl.handle.net/11562/1097568
https://hdl.handle.net/11562/1097568
In this microreview, the authors summarize the reactions of [Pt3n(CO)6n]2-(n = 1-10) Chini clusters aimed at their functionalization, modification and transformation. The results are organized on the basis of the fact that the final products do or do
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::5922a5af85861e4bd578eb192c2e81d1
https://hdl.handle.net/11562/1097569
https://hdl.handle.net/11562/1097569
Autor:
Maria Carmela Iapalucci, Stefano Zacchini, Iacopo Ciabatti, Cristina Femoni, Giuliano Longoni, Enrico Cattabriga
The thermal decomposition of [Pt3n(CO)6n]2− (n = 2–10) Chini clusters results in the formation of globular molecular platinum carbonyl clusters, whose nature depends of the nuclearity of the parent cluster as well as the counter-ion and solvent e
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::0269311966d4bd8c6de9ebe5deab0f89
http://hdl.handle.net/11585/617901
http://hdl.handle.net/11585/617901
Autor:
Stefano Zacchini, Cristina Femoni, Stefano Merighi, Iacopo Ciabatti, Maria Carmela Iapalucci, Tiziana Funaioli
This paper reports a detailed study of the oxidation and reduction reactions of simple nickel mono-carbide and mono-acetlyde carbonyl clusters. The reduction of [Ni 9 C(CO) 17 ] 2– with Na/naphtalene affords the new [Ni 12 C(CO) 18 ] 4– mono-carb
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::d07871f744caebc94a3bdead4155260f
http://hdl.handle.net/11585/613482
http://hdl.handle.net/11585/613482
Autor:
Cristiana Cesari, Maria Carmela Iapalucci, Iacopo Ciabatti, Stefano Zacchini, Cristina Femoni, Federica Mancini
none 6 no The reactions of [Pt3n(CO)6n]2- (n = 2-4) homoleptic Chini-type clusters with stoichiometric amounts of Ph2PCH2CH2PPh2 (dppe) result in the heteroleptic Chini-type clusters [Pt6(CO)10(dppe)]2-, [Pt9(CO)16(dppe)]2-, and [Pt12(CO)20(dppe)2]2-
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::de78360a4ccd5cb80c9d374b9771f28d
http://hdl.handle.net/11585/585180
http://hdl.handle.net/11585/585180