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Publikováno v:
J. Chem. Soc., Dalton Trans.. :1641-1645
The compounds [MCl(CPhCMe2)(η-C5H5)2](M = Zr or Hf) and [TiCl0.5Br0.5(CPhCMe2)(η-C5H5)2], whose structures have been determined by X-ray diffraction, all show a π-type of interaction between the phenyl ring and the metal. This is revealed by (i) t