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Publikováno v:
Digital.CSIC. Repositorio Institucional del CSIC
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The divergent gold-catalysed reactivity (Csp 2-H versus Csp 3-H) of aryloxy-tethered allenes has been uncovered. © 2012 The Royal Society of Chemistry.
Autor:
Mireia Toledano-Pinedo, Pedro Almendros, Guillermo Palop, Teresa Martínez del Campo, Laura Martín, Benito Alcaide
Publikováno v:
Digital.CSIC. Repositorio Institucional del CSIC
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The controlled preparation of two types of α-seleno-α,β-unsaturated carbonyls, namely, α-selenoenals and α-selenoenones, has been accomplished directly from allenes through metal-free oxidative selenofunctionalization reactions. The decisive rol