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Autor:
Giuliano Longoni, Iacopo Ciabatti, Stefano Zacchini, Alessandro Bernardi, Maria Carmela Iapalucci, Cristina Femoni
Publikováno v:
Journal of Organometallic Chemistry. 812:229-239
The reaction of [Ni 10 (C 2 ) (CO) 16 ] 2– with CuCl in thf affords [Ni 45 C 10 (CO) 46 ] 6– as the major product. This represents the first deca-carbide carbonyl cluster and this is the highest number of C-atoms found in a molecular cluster. Bes