Zobrazeno 1 - 2
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pro vyhledávání: '"Ludger Heiliger"'
Publikováno v:
Journal of the American Chemical Society. 114:7737-7742
Comparison of ab initio/IGLO calculated 1 H, 13 C, and 29 Si NMR chemical shifts with the experimental data on trimethylsilyl perchlorate and related derivatives supports the conclusions that no long-lived persistent trimethylsilicenium ion has been
Autor:
George A. Olah, Raymond C. Stevens, G. K. Surya Prakash, Schahab Keyaniyan, Ludger Heiliger, Robert Aniszfeld, Hok Kin Choi, Robert Bau
Publikováno v:
Journal of the American Chemical Society. 109:5123-5126
/sup 29/Si and /sup 35/Cl NMR spectroscopic and X-ray crystallographic study of triphenylsilyl perchlorate shows it to be a covalent perchloryl ester in both solution and the solid state. The results are in accord with earlier studies notably those o