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Autor:
Marco Bonizzoni, Maurizio Licchelli, Carlo Ciarrocchi, Michele Invernici, Simone Lazzaroni, Massimo Boiocchi, Luigi Fabbrizzi, Daniele Dondi
Publikováno v:
ACS Omega
ACS Omega, Vol 3, Iss 11, Pp 15692-15701 (2018)
ACS Omega, Vol 3, Iss 11, Pp 15692-15701 (2018)
The dicopper(II) complex of the bimacrocyclic ligand α,α′-bis(5,7-dimethyl-1,4,8,11-tetraazacyclotetradecan-6-yl)-o-xylene, 2, interacts with selected anions in dimethyl sulfoxide solution according to two different modes: (i) halides (Cl–, Br
Autor:
Tsubasa Yoneuchi, Satoru Takakusagi, Masaru Kato, Yuki Wakisaka, Shin Ichiro Noro, Yohei Uemura, Ichizo Yagi, Takashi Tokushima, Tomoko Ishihara, Kiyotaka Asakura, Marika Muto, Daiju Matsumura, Naohiro Matsubara
Publikováno v:
ACS Applied Energy Materials. 1(5):2358-2364
Multinuclear metal active sites are widely used as catalytic reaction centers in metalloenzymes and generally show high catalytic activity. For example, laccases are known to catalyze the oxygen reduction reaction (ORR) to water at a multinuclear cop
Autor:
Willi Auwärter, Chiara Fabbro, Knud Seufert, Claudia Aurisicchio, Davide Bonifazi, Johannes V. Barth, David Écija, Daniel Heim
Publikováno v:
Journal of the American Chemical Society. 132(19):6783-6790
We employed a de novo synthesized porphyrin module to construct one-dimensional (1D) Cu-coordinated polymers on Cu(111) and Ag(111) surfaces. The programmed geometry and functionality of the molecular module together with its conformational flexibili