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The thiazolium catalyzed benzoin condensation with mild base does not involve a 'dimer' intermediate
Autor:
Ronald Breslow, Ronald Kim
Publikováno v:
Tetrahedron Letters. 35:699-702
Kinetic studies show that the benzoin condensation catalyzed by 3,4,5-trimethylthiazolium iodide and triethylamine in DMSO has a transition state with two benzaldehyde and one thiazolium components, while the conversion of nitrobenzaldehyde to the th