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pro vyhledávání: '"Yinhua Huang"'
Autor:
Yinhua Huang, Xiaosa Lu
Publikováno v:
Organic Chemistry Frontiers. 8:3008-3013
Rhodium-catalyzed stereospecific cyanation of the olefinic C–H bond using environmentally benign N-cyano-N-phenyl-p-methylbenzenesulfonamide (NCTS) as a cyanating reagent for the synthesis of β,β-disubstituted acrylonitriles has been developed. T
Publikováno v:
Organic Chemistry Frontiers. 8:5699-5704
A Cu-catalyzed highly selective silylation and borylation of alkenylsulfonium salts under mild conditions is reported. The reaction provides easy access to various alkenylsilanes and alkenylboranes by forming a C–Si/B bond at the alkenyl moiety of