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Publikováno v:
Journal of the Chemical Society A: Inorganic, Physical, Theoretical. :1909
The phosphines R(RF)2P (RF= CF3, R = Me, Bun, Bui, Ph; RF= C3F7, R = Bun, Ph) and Bu2n(CF3)P, and the phosphinous chloride Bu(CF3)PCl, have been made from the chlorides (RF)2PCl or RFPCl2 and organolithium compounds in ether–hexane at –78°. The
Publikováno v:
Journal of the Chemical Society A: Inorganic, Physical, Theoretical. :930
Prop-2-ynyl chloride forms stable σ-prop-2-ynyl complexes with the anions [Mn(CO)4PPh3]– and [Mn(CO)3(PPh3)2]–. The compound [(CH⋮C·CH2)Mn(CO)4(PPh3)] reacts with the acids RCO2H (R = Me, Et, or ClCH2) to afford stable 1 : 1 adducts of the ty
Publikováno v:
Journal of the Chemical Society A: Inorganic, Physical, Theoretical. :541
Anhydrous Chromium(III) chloride has been treated with the tertiary phosphines Me3P, Et3P, Bun3P, PhPEt2, and Ph2PEt by heating under reflux in benzene or toluene at 60°. Only in the first three cases did reaction take place and only for Et3P and Bu
Autor:
C. Masters, B. L. Shaw
Publikováno v:
Journal of the Chemical Society A: Inorganic, Physical, Theoretical. :3679
Paramagnetic rhodium(II) complexes of the type trans-[RhCl2(PBut2R)2](R = Me, Et, or Prn) are formed rapidly by treating ethanolic rhodium(III) chloride trihydrate with the tertiary phosphine at 25 °C. The complexes have low magnetic moments in the
Publikováno v:
Journal of the Chemical Society A: Inorganic, Physical, Theoretical. :3166
Heptafluoroiodo-n-propane and pentafluorobenzoyl chloride oxidatively add to acetylacetonatobis(methyldiphenylphosphine)rhodium to form the rhodium(III) complexes [Rh(acac)(Ph2PMe)2(C3F7)I] and [Rh(acac)(Ph2PMe)2(COC6F5)Cl]. Treatment of [Rh(L)2(acac
Autor:
D. M. P. Mingos, J. Chatt
Publikováno v:
Journal of the Chemical Society A: Inorganic, Physical, Theoretical. :1770
The p-toluenesulphinatoplatinum(II) complexes, cis- and trans-[PtX(SO2tol)(PR3)2], [Pt2Cl2(SO2tol)2(PR3)2], [Pt2(SnCl3)2(SO2tol)2(PR3)2], [Pt2Cl3(SO2tol)(PR3)2], and [Pt2Cl(SnCl3)2(SO2tol)(PR3)2](X = Cl or Br; PR3= tertiary phosphine and tol =p-tolyl
Autor:
R. A. Walton, R. Whyman
Publikováno v:
Journal of the Chemical Society A: Inorganic, Physical, Theoretical. :1394
Nicke(II) chloride and bromide react with tri-(2-cyanoethyl)phosphine (CEP) in acetone to form the red squareplanar complexes α-NiX2,2CEP. These complexes transform to the blue paramagnetic β-forms at room temperature and above. Cobalt(II) chloride
Autor:
E. A. C. Lucken
Publikováno v:
Journal of the Chemical Society A: Inorganic, Physical, Theoretical. :1357
Trishydroxymethylphosphine, trishydroxymethylphosphine oxide, and tetrakishydroxymethylphosphonium chloride have been allowed to react with hydroxy radicals, and the electron spin resonance spectra of the resulting species observed using a high-speed