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Publikováno v:
Journal of the Chemical Society A: Inorganic, Physical, Theoretical. :1733
The reaction of tris(triphenylphosphine)chlororhodium(I) with iodomethane is shown to give an octahedral complex of rhodium(III), [RhlCl(CH3)(PPh3)2(ICH3)], which contains not only a Rh–CH3 group, but also unusually, a firmly co-ordinated iodometha
Autor:
J. L. Dawes, R. D. W. Kemmitt
Publikováno v:
Journal of the Chemical Society A: Inorganic, Physical, Theoretical. :2093
The adducts [RhX(1,5-C8H12)]2,2HgX2(X = Cl or Br) have been prepared by the action of mercuric halide on [RhX(1,5-C8H12)]2. Mercuric chloride and the mononuclear complexes RhCl(1,5-C8H12)L (L = Ph3P or piperidine), also give the adduct [RhCl(1,5-C8H1
Publikováno v:
Journal of the Chemical Society A: Inorganic, Physical, Theoretical. :1909
The phosphines R(RF)2P (RF= CF3, R = Me, Bun, Bui, Ph; RF= C3F7, R = Bun, Ph) and Bu2n(CF3)P, and the phosphinous chloride Bu(CF3)PCl, have been made from the chlorides (RF)2PCl or RFPCl2 and organolithium compounds in ether–hexane at –78°. The
Autor:
C. K. Chu, J. D. Murray
Publikováno v:
Journal of the Chemical Society A: Inorganic, Physical, Theoretical. :360
The hydrolysis of di-s-butyltin dichloride yields similar products to those found for the di-n-butyl compound whereas the hydrolysis behaviour of di-t-butyltin dichloride is markedly different. Distannoxanes are not found in the latter case but inste
Autor:
Alan G. MacDiarmid, Bernard Cohen
Publikováno v:
Journal of the Chemical Society A: Inorganic, Physical, Theoretical. :1780
Pentafluorosulphur chloride, SF5Cl, reacts with trimethylamine at –78° to give SF5Cl,(NMe3)2. This compound decomposes quantitatively at room temperature to yield sulphur tetrafluoride and (Me3N)2CIF.Methyliminosulphur difluoride, CH3NSF2, has bee
Publikováno v:
Journal of the Chemical Society A: Inorganic, Physical, Theoretical. :930
Prop-2-ynyl chloride forms stable σ-prop-2-ynyl complexes with the anions [Mn(CO)4PPh3]– and [Mn(CO)3(PPh3)2]–. The compound [(CH⋮C·CH2)Mn(CO)4(PPh3)] reacts with the acids RCO2H (R = Me, Et, or ClCH2) to afford stable 1 : 1 adducts of the ty
Publikováno v:
Journal of the Chemical Society A: Inorganic, Physical, Theoretical. :612
The reduction of nitrobenzene, nitrosobenzene, and azoxybenzene by potassium borohydride is catalysed by hydroxocobalamin. The products of the reaction with nitrobenzene include aniline and azobenzene. The cobalt(I) cobalamin, vitamin B12s, reacts wi
Publikováno v:
Journal of the Chemical Society A: Inorganic, Physical, Theoretical. :1964
Improved syntheses of tetracarbonylcyclo-octafluorotetramethyleneiron by u.v. irradiation of tetrafluoroethylene with either nonacarbonyldi-iron or a mixture of pentacarbonyliron and dodecacarbonyltri-iron are described. Ligands displace carbon monox
Publikováno v:
Journal of the Chemical Society A: Inorganic, Physical, Theoretical. :1612
Boron trichloride and the N-substituted benzimidoyl chlorides PhCCl:NR (R = Me, Et, or Ph) form 1:1 adducts which are formulated as nitrilium tetrachloroborates PhCNR+BCl4– on the basis of their infrared spectra, which have ν(CN) at 2380, 2365, an
Autor:
A. L. Allred, S. A. Kandil
Publikováno v:
Journal of the Chemical Society A: Inorganic, Physical, Theoretical. :2987
Several t-butyltin derivatives including the tri-t-butyltin chloride and iodide were synthesized. Experiments designed for the synthesis of tetra-t-butyltin by the reaction of tri-t-butyltin halide with t-butyl-lithium led to the isolation of hexa-t-