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Autor:
Z. Goffer, M. J. Frazer
Publikováno v:
Journal of the Chemical Society A: Inorganic, Physical, Theoretical. :544
The adducts MCl4noxH (M = Sn or Ti)(n= 1 or 2) are precipitated when 8-quinolinol (oxH) and the appropriate tetrahalides are mixed in chloroform. In these adducts the ligand 8-quinolinol is probably unidentate. Solids having the same composition, but
Autor:
M. V. Park
Publikováno v:
Journal of the Chemical Society A: Inorganic, Physical, Theoretical. :816
The complexes formed by salicyluric acid and several substituted derivatives of salicylic acid with ferric ions have been investigated at 25° and in a medium of ionic strength 0·1 using pH and oxidation-potential measurements. The equilibrium const
Publikováno v:
Journal of the Chemical Society A: Inorganic, Physical, Theoretical. :1409
In acid conditions and the presence of 7% of water, the principal products of the ferric ion-catalysed oxidation of ethanol by hydrogen peroxide are acetaldehyde and diethylacetal. The rate-determining step is shown to be independent of acidity and i
Autor:
S. A. Cotton, J. F. Gibson
Publikováno v:
Journal of the Chemical Society A: Inorganic, Physical, Theoretical. :1696
The complexes Fe(pyrazole)3Cl3, Fe(3-methylpyrazole)3Cl3, Fe(py)4Cl3, Fe(pyrimidine)2Cl3, and Fe(pyrazine)5/2Cl3 have been prepared; the vibrational spectra of these and a number of similar, indium complexes have been recorded and metal–nitrogen an
Autor:
R. A. Basson, T. A. du Plessis
Publikováno v:
Journal of the Chemical Society A: Inorganic, Physical, Theoretical. :778
Addition of ethylene to oxygenated aqueous ferrous sulphate solutions increases the radiolytic yield of ferric ion. Formaldehyde and acetaldehyde are also found as radiolysis products. Ferric yields are linear with does between 2 × 1017 and 1018 eV/
Autor:
D. Dollimore, D. Nicholson
Publikováno v:
Journal of the Chemical Society A: Inorganic, Physical, Theoretical. :281
Ferric oxalate on thermal decomposition produces an oxide with a porous structure which differs according to the nature of the heat treatment. In particular, there is a marked difference between samples heated directly at temperatures around 400°C a
Autor:
M. A. Place, A. G. Foster
Publikováno v:
Journal of the Chemical Society A: Inorganic, Physical, Theoretical. :556
Adsorption isotherms are reported for a series of aliphatic nitriles on a ferric oxide gel and on a silica gel.
Autor:
A. K. Galwey
Publikováno v:
Journal of the Chemical Society A: Inorganic, Physical, Theoretical. :87
Ferric, cobalt, and nickel salts of mellitic acid have been prepared as crystalline hydrates which, when heated in vacuo, dehydrate to give almost amorphous substances.On heating in vacuo, the cobalt and nickel salts decomposed completely in a single
Autor:
P. Day, N. Sanders
Publikováno v:
Journal of the Chemical Society A: Inorganic, Physical, Theoretical. :1536
Measurement of the charge-transfer band of tris(phenanthroline)iron(II) at low temperature provides supports for the suggestion that its fine structure arises from a vibrational progression in the excited state.A one-electron theory of charge-transfe